| Identification | Back Directory | [Name]
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(II) | [CAS]
2049086-36-2 | [Synonyms]
CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYL(DIPHENYLPHOSPHINE)}NICKEL(II)
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II) >=95% | [Molecular Formula]
C43H48ClFeNNiP2 | [MDL Number]
MFCD31619173 | [MOL File]
2049086-36-2.mol | [Molecular Weight]
785.76 |
| Chemical Properties | Back Directory | [form ]
solid | [color ]
orange | [SMILES]
C[Ni+]C1=CC=C(C#N)C=C1.[C]2(CP(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe] |
| Questions And Answer | Back Directory | [Uses]
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(II) is useful in these fields:
- Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions.
- Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines
- Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions
- Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts
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