| Identification | Back Directory | [Name]
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]- | [CAS]
2230788-67-5 | [Synonyms]
cataCXium A Pd G4
Formed catalyst cataCXium? A Pd G4
Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)-2-(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
(cataCXium Pd G4)
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]- | [Molecular Formula]
C38H54NO3PPdS | [MDL Number]
MFCD31692233 | [MOL File]
2230788-67-5.mol | [Molecular Weight]
742.31 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light | [form ]
solid | [Appearance]
Off-white to gray Solid | [InChIKey]
FOIUZOZBEHPFHG-UHFFFAOYSA-N | [SMILES]
P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)([Pd+2]1(N(C2=CC=CC=C2C2=CC=CC=[C-]12)C)[O-]S(=O)(=O)C)CCCC |
| Hazard Information | Back Directory | [Uses]
A fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents. | [reaction suitability]
reagent type: catalyst
core: palladium
reaction type: Cross Couplings |
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