| Identification | Back Directory | [Name]
Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% [P(t-Bu)3 Palladacycle Gen. 4] | [CAS]
1621274-11-0 | [Synonyms]
P(t-Bu)3 Pd G4 | [Molecular Formula]
C26H42NO3PPdS | [MDL Number]
MFCD28411657 | [MOL File]
1621274-11-0.mol | [Molecular Weight]
651.047 |
| Chemical Properties | Back Directory | [form ]
Powder | [color ]
tan to yellow | [InChI]
InChI=1S/C14H15N.3C4H10P.O3S.Pd/c1-11-7-3-4-8-12(11)13-9-5-6-10-14(13)15-2;3*1-4(2,3)5;1-4(2)3;/h3-10,15H,1-2H3;3*5H,1-3H3;;/q;4*-1;+1 | [InChIKey]
JBZFBSFINJJLAH-UHFFFAOYSA-N | [SMILES]
CC1=CC=CC=C1C1=CC=CC=C1NC.[Pd-2](S([O-])(=O)=O)(PC(C)(C)C)(PC(C)(C)C)PC(C)(C)C | [CAS DataBase Reference]
1621274-11-0 |
| Hazard Information | Back Directory | [Chemical Properties]
P(t-Bu)3 Pd G4 is a powder or crystalsis,it's stable, soluble in most organic solvents. | [Uses]
P(t-Bu)3 Pd G4 (Cas:1621274-11-0)is a powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reactions]
- Alternative Pd-catalyzed cross-coupling reaction of s-BuB(OH)2 and 4-chloroanisole.
- Alternative Pd-catalyzed cross-coupling reaction of secondary alkylboronic acids and aryl chlorides.
- Alternative Pd-catalyzed cross-coupling reaction of secondary alkyltrifluoroborates and aryl chlorides
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