ChemicalBook--->CAS DataBase List--->2269-22-9

2269-22-9

2269-22-9 Structure

2269-22-9 Structure
IdentificationMore
[Name]

Aluminium tri-sec-butoxide
[CAS]

2269-22-9
[Synonyms]

ALUMINIUM S-BUTOXIDE
ALUMINIUM SEC-BUTOXIDE
ALUMINIUM SEC-BUTYLATE
ALUMINIUM TRI-S-BUTOXIDE
ALUMINIUM TRI-SEC-BUTANOLATE
ALUMINIUM TRI-SEC-BUTOXIDE
ALUMINIUM TRI-SEC-BUTYLATE
ALUMINUM(III)S-BUTOXIDE
ALUMINUM S-BUTOXIDE
ALUMINUM SEC-BUTOXIDE
ALUMINUM SEC-BUTYLATE
ALUMINUM TRI-SEC-BUTOXIDE
ALUMINUM TRI-SEC-BUTYLATE
ASB
2-Butanol, aluminum salt
2-Butanol,aluminumsalt
Aluminum isobutylate
ALUMINUM TRI-SEC-BUTOXIDE, 99+%
ALUMINUM TRI-SEC-BUTOXIDE, 1.0M IN DICHLOROMETHANE
Aluminum s-butoxide, 98+%
[EINECS(EC#)]

218-871-2
[Molecular Formula]

C12H27AlO3
[MDL Number]

MFCD00009327
[Molecular Weight]

246.32
[MOL File]

2269-22-9.mol
Chemical PropertiesBack Directory
[Appearance]

viscous colourless or pale yellow liquid
[Boiling point ]

40 °C
[density ]

0.967 g/mL at 25 °C(lit.)
[vapor pressure ]

23 hPa (195 °C)
[refractive index ]

1.4390
[Fp ]

82 °F
[storage temp. ]

Flammables area
[solubility ]

Miscible with alcohol, isopropyl alcohol and toluene.
[form ]

Oily Liquid
[color ]

Light yellow
[Specific Gravity]

0.9671
[Stability:]

Stability Stable, but may decompose upon exposure to air and moisture. Flammable. Incompatible with strong oxidizing agents, strong acids, water.
[explosive limit]

1.7-9.8%(V)
[Water Solubility ]

decomposes
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Moisture Sensitive
[BRN ]

3910908
[Cosmetics Ingredients Functions]

LIGHT STABILIZER
[InChI]

1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
[InChIKey]

WOZZOSDBXABUFO-UHFFFAOYSA-N
[SMILES]

CCC(C)O[Al](OC(C)CC)OC(C)CC
[CAS DataBase Reference]

2269-22-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Aluminum tri-sec-butoxide(2269-22-9)
[EPA Substance Registry System]

2269-22-9(EPA Substance)
Questions And AnswerBack Directory
[Preparation]

Preparation method of Aluminium tri-sec-butoxide: In a 3-liter three-necked flask equipped with a reflux condenser, add 0.15 kg (excess) of 99% pure aluminum granules, 0.15 g of anhydrous aluminum trichloride, and 1 kg of sec-butyl acetate solvent. Then add 0.33 kg of sec-butanol, stir, heat, and reflux at approximately 100°C. After 2 hours, a black solution containing aluminum iso-sec-butoxide is obtained. The solution is pumped out and allowed to settle for 15 hours. The upper colorless and transparent solution containing 30% Aluminium tri-sec-butoxide is then removed. Distillation begins at 110°C. As sec-butyl acetate evaporates, the distillation temperature is gradually increased until it reaches 125°C. Heating is then stopped, and the product, Aluminium tri-sec-butoxide, is obtained after cooling.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Skull and Crossbones (GHS06)
GHS02,GHS06
[Signal word ]

Danger
[Hazard statements ]

H226-H302-H311
[Precautionary statements ]

P210-P280-P301+P312+P330-P302+P352+P312
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R40:Limited evidence of a carcinogenic effect.
R21/22:Harmful in contact with skin and if swallowed .
R10:Flammable.
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 1992 3/PG 3
[WGK Germany ]

3
[F ]

3-10-23
[Autoignition Temperature]

763 °F
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29051900
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 4 Oral
Flam. Liq. 3
[Toxicity]

LD50 orally in Rabbit: 401 mg/kg LD50 dermal Rabbit 402 mg/kg
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Aluminium tri-sec-butoxide(2269-22-9).msds
Hazard InformationBack Directory
[Chemical Properties]

viscous colourless or pale yellow liquid
[Uses]

It is used for active catalyst and support, inorganic membrane, redrcing agent of aldehyde-ketone, oxidant of aldehyde-ketone, gel forming agent of printing ink and paint, dehydrant, water proofing agent and aluminum base grease.
[Flammability and Explosibility]

Flammable
[reaction suitability]

core: aluminum
Spectrum DetailBack Directory
[Spectrum Detail]

Aluminium tri-sec-butoxide(2269-22-9)MS
Aluminium tri-sec-butoxide(2269-22-9)13CNMR
Aluminium tri-sec-butoxide(2269-22-9)IR1
Aluminium tri-sec-butoxide(2269-22-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Aluminium tri-sec-butoxide, 97%(2269-22-9)
[Alfa Aesar]

Aluminum sec-butoxide, 97%(2269-22-9)
[Sigma Aldrich]

2269-22-9(sigmaaldrich)
[TCI AMERICA]

Aluminum sec-Butoxide,>98.0%(T)(2269-22-9)
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