| Identification | More | [Name]
TRIS(DIETHYLAMINO)PHOSPHINE | [CAS]
2283-11-6 | [Synonyms]
AURORA KA-1249
HEXAETHYLPHOSPHOROUS TRIAMIDE
HEXAETHYLPHOSPHORUS TRIAMIDE
HEXAETHYLTRIAMINOPHOSPHINE
TIMTEC-BB SBB008031
TRIS(DIETHYLAMINO)PHOSPHINE
hexaethyl-phosphoroustriamid
Hexaethylphosphoruo triamide
P(N(C2H5)2)3
Tris(N,N-diethylamino)phosphine
Hexaethyl phosphorous triamide, 97+%
Phosphorous triamide, hexaethyl-
Tri(diethylamino)phosphine | [EINECS(EC#)]
218-920-8 | [Molecular Formula]
C12H30N3P | [MDL Number]
MFCD00009041 | [Molecular Weight]
247.36 | [MOL File]
2283-11-6.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to yellow-orange liquid | [Melting point ]
230-232 °C | [Boiling point ]
80-90 °C10 mm Hg(lit.) | [density ]
0.903 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.475(lit.)
| [Fp ]
58 °C
| [storage temp. ]
Store below +30°C. | [form ]
Liquid | [pka]
9.74±0.70(Predicted) | [color ]
Clear colorless to yellow-orange | [Specific Gravity]
0.903 | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Air Sensitive | [BRN ]
636187 | [CAS DataBase Reference]
2283-11-6(CAS DataBase Reference) | [EPA Substance Registry System]
Phosphorous triamide, hexaethyl- (2283-11-6) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [F ]
10-23 | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to yellow-orange liquid | [Uses]
Tris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize:
- 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.
- 1-Aminomethylisatins by treating with isatin and primary and secondary amines.
It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60. | [Uses]
suzuki reaction | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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