| Identification | More | [Name]
(S)-(+)-alpha-Methoxyphenylacetic acid | [CAS]
26164-26-1 | [Synonyms]
O-METHYL-L-MANDELIC ACID
(S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID
(S)-ALPHA-METHOXYPHENYLACETIC ACID
(S)-(+)-A-METHOXYPHENYLACETIC ACID
(S)-(+)-METHOXYPHENYLACETIC ACID
Methoxy(phenyl)acetic acid
(S)-(+)-A-METHOXYPHENYLACETIC ACID FLU&
O-Methyl-(S)-mandelicacid
(s)-(+)-à-methoxyphenylacetic acid
(S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID 99%
(S)-(+)-ɑ-Methoxyphenylacetic acid, 99%
(2S)-2-Methoxy-2-phenylacetic acid
(S)-α-Methoxybenzeneacetic acid
(αS)-α-Methoxybenzeneacetic acid
[S,(+)]-α-Methoxybenzeneacetic acid | [EINECS(EC#)]
247-492-5 | [Molecular Formula]
C9H10O3 | [MDL Number]
MFCD00064216 | [Molecular Weight]
166.17 | [MOL File]
26164-26-1.mol |
| Chemical Properties | Back Directory | [Appearance]
White Solid | [Melting point ]
64-66 °C(lit.) | [alpha ]
160 º (C=1, MEOH) | [Boiling point ]
164-166°C 18mm | [density ]
1.1708 (rough estimate) | [refractive index ]
147 ° (C=0.5, EtOH) | [Fp ]
164-166°C/18mm | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Ethanol (Slightly) | [form ]
Fine Crystalline Powder or Crystals | [pka]
3.10±0.10(Predicted) | [color ]
White | [Optical Rotation]
[α]17/D +150°, c = 1 in ethanol | [Water Solubility ]
Soluble | [BRN ]
2361718 | [CAS DataBase Reference]
26164-26-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzeneacetic acid, «alpha»-methoxy-, (s)-(26164-26-1) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29189900 |
| Hazard Information | Back Directory | [Chemical Properties]
White Solid | [Uses]
(S)-(+)-α-Methoxyphenylacetic Acid (cas# 26164-26-1) is a compound useful in organic synthesis. | [Uses]
Reactant involved in the synthesis of biologically active molecules including:
- Acyclonucleoside phosphonates structural analogs of adefovir
- Labeled discodermolide for studying binding to tubulin
- 10-Isocyano-4-cadinene used for antifouling activity
Reactant involved in studies of immunostimulating chromanones gonytolides A-C
Reactant involved in:
- Hydroxylations and epoxidations
- Hydrogenations
| [Purification Methods]
Purify the acids by recrystallising from *C6H6/pet ether (b 80-100o). [Neilson & Peters J Chem Soc 1519 1962, Weizmann et al. J Am Chem Soc 70 1153 1948, Pirie & Smith J Chem Soc 338 1932, NMR: Dale & Mosher J Am Chem Soc 9 5 512 1973, for resolution: Roy & Deslongchamps Can J Chem 63 651 1985, Trost et al. J Am Chem Soc 1 0 8 4974 1986.] The racemic mixture has m 72o, b 121-122o/0.4mm, 165o/18mm (from pet ether) [Braun et al. Chem Ber 6 3 2847 1930]. [Beilstein 10 IV 566.] |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
|