| Identification | Back Directory | [Name]
1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE | [CAS]
282109-83-5 | [Synonyms]
SIPr-HBF4
Bisdiisopropylphenyldihydroimidazoliumtetrafluorobora
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydroiMidazoliuM tetraf
1,3-BIS(2,6-DIISOPROPYLPHENYL) IMIDAZOLIDINIUM TETRAFLUOROBORATE, 97+%
1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
1,3-BIS(2,6-DI-ISOPROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,95%
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium tetrafluoroborate 95%
1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazolium tetrafluoroborate, 97+%
1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,min.95%
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-iMidazol-3-iuM tetrafluoroborate
1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE, MIN. 95%
SIPr-HBF4, N,Nμ-Bis(2,6-diisopropylphenyl)dihydroimidazolium tetrafluoroborate, 4,5-Dihydro-1,3-bis(2,6-diisopropylphenyl)imidazolium tetrafluoroborate | [Molecular Formula]
C27H39BF4N2 | [MDL Number]
MFCD03412153 | [MOL File]
282109-83-5.mol | [Molecular Weight]
478.42 |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
>300 | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
White | [InChI]
InChI=1S/C27H39N2.BF4/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2-1(3,4)5/h9-14,17-21H,15-16H2,1-8H3;/q+1;-1 | [InChIKey]
KFZBJQUHHALFSR-UHFFFAOYSA-N | [SMILES]
C1(=C(C(C)C)C=CC=C1C(C)C)N1CC[N+](C2C(C(C)C)=CC=CC=2C(C)C)=C1.[B-](F)(F)(F)F |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
20-34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 1759 8/PG 2 | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
29332990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Acute Tox. 4 Inhalation
Eye Dam. 1
Skin Corr. 1B |
| Questions And Answer | Back Directory | [Reaction]
In-situ deprotonation leads to metal carbene species which acts as a catalyst in a variety of C-C and C-N bond forming reactions.
- Ligand used in the nickel or palladium-catalyzed coupling of aryl chlorides and amines.
- Ligand used for the palladium-catalyzed arylation of esters and amides.
- Ligand used for the palladium-catalyzed intermolecular amination of Csp3–H Bonds.
- Ligand used for the nickel-catalyzed hydrogenation of olefins.
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