| Identification | More | [Name]
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE | [CAS]
245679-18-9 | [Synonyms]
3-BIS(2
SIMesBF4
SIMes-HBF4
ium tetrafL
6-TRIMETHYLPHENYL)-4
)-4,5-dihydroimidazoL
5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimid
4,5-Dihydro-1,3-dimesitylimidazolium tetrafluoroborate
4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium
4,5-Dihydro-1,3-dimesityl-1H-imidazolium tetrafluoroborate
1,3-Bis(2,4,6-triMethylphenyl)-4,5-dihydroiMidazoliuM tetraf
1,3-DiMesityl-4,5-dihydro-1H-iMidazol-3-iuM tetrafluoroborate
1,3-bis(2,4,6-trimethylphenyl)imidazolidin-1-ium tetrafluoroborate
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate95+%
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-1-ium,tetrafluoroborate
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium tetrafluoroborate, 97+%
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,min.95%
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE, MIN. 95%
1,3-BIS-(2,4,6-TRIMETHYL-PHENYL)-4,5-DIHYDRO-3H-IMIDAZOL-1-IUM TETRAFLUORO BORATE
1,3-Bis(2,4,6-triMethylphenyl)-4,5-dihydroiMidazoliuM tetrafluoroborate SIMes·HBF4
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium tetrafluoroborate, min. 95% SIMes-HBF4
4,5-Dihydro-1,3-dimesitylimidazolium tetrafluoroborate, SIMes-HBF4, 4,5-Dihydro-1,3-dimesityl-1H-imidazolium tetrafluoroborate, 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium tetrafluoroborate(1-) | [Molecular Formula]
C21H27BF4N2 | [MDL Number]
MFCD02684542 | [Molecular Weight]
394.26 | [MOL File]
245679-18-9.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
290-296 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
off-white | [InChI]
1S/C21H27N2.BF4/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;2-1(3,4)5/h9-13H,7-8H2,1-6H3;/q+1;-1 | [InChIKey]
VNRDQIOMNLIVQJ-UHFFFAOYSA-N | [SMILES]
F[B-](F)(F)F.Cc1cc(C)c(N2CC[N+](=C2)c3c(C)cc(C)cc3C)c(C)c1 | [CAS DataBase Reference]
245679-18-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R20:Harmful by inhalation. | [Safety Statements ]
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 1759 8/PG 2 | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
29332990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Acute Tox. 4 Inhalation
Eye Dam. 1
Skin Corr. 1B |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for ruthenium-catalyzed selective reduction of nitriles to primary amines.
- Ligand for nickelcatalyzed [2+2+2] cycloaddition of arynes and an unactivated alkene.
- Ligand for copper-catalyzed [3+2] cycloaddition of azides and alkynes under mild conditions.
- Ligand for copper-catalyzed direct aryl quaternization of N-substituted imidazoles to form imidazolium salts.
- Ligand for copper-catalyzed silylation of allenes.
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