| Identification | More | [Name]
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine | [CAS]
309-88-6 | [Synonyms]
1,1,2,3,3,3-HEXAFLUORO-1-DIETHYLAMINO-PROPAN
1,1,2,3,3,3-HEXAFLUORO-1-DIETHYLAMINOPROPANE
ISHIKAWA'S REAGENT
MEC-81
N,N-DIETHYL-1,1,2,3,3,3-HEXAFLUOROPROPYLAMINE
SHIKAWA'S REAGENT
Ishikawas
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine, 40-50% in diglyme
Hexafluoro-1-diethylamino-propane
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine 97%
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine97%
ISHIKAWA''S REAGENT: TECH., 90%
DIETHYL-(1,1,2,3,3,3-HEXAFLUOROPROPYL)AMINE
Ishikawa's Reagent [Fluorinating Reagent]
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine
1,1,2,3,3,3-Hexafluoropropyldiethylamine
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropane-1-amine | [EINECS(EC#)]
628-698-8 | [Molecular Formula]
C7H11F6N | [MDL Number]
MFCD00054683 | [Molecular Weight]
223.16 | [MOL File]
309-88-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to yellow liquid | [Boiling point ]
56-57 °C (lit.) | [density ]
1.23 | [refractive index ]
1.3460 | [Fp ]
56-57°C/58mm | [storage temp. ]
Flammables area | [solubility ]
soluble in Acetone,Ether | [form ]
Liquid | [pka]
1.50±0.70(Predicted) | [color ]
Clear colorless to yellow | [Specific Gravity]
1.230 | [Merck ]
5108 | [InChI]
1S/C7H11F6N/c1-3-14(4-2)7(12,13)5(8)6(9,10)11/h5H,3-4H2,1-2H3 | [InChIKey]
BNTFCVMJHBNJAR-UHFFFAOYSA-N | [SMILES]
CCN(CC)C(F)(F)C(F)C(F)(F)F | [CAS DataBase Reference]
309-88-6(CAS DataBase Reference) | [EPA Substance Registry System]
N,N-Diethyl-2H-perfluoropropanamine (309-88-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R10:Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
3267 | [WGK Germany ]
3 | [Hazard Note ]
Corrosive | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29211999 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 3
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to yellow liquid | [Uses]
Reactant for:
- Friedel-Crafts type arylation of hydrofluorocarbons
- Microbial hydroxylation of antibiotics
- Electrochemical fluorination of trialkylamines and tetraalkylammonium salts
- Fluorination of pyrethroides
Reactant for synthesis of:
- γ-Hydroxy-α-fluoro-α-trifluoromethylcarboxamide
- Florfenicol and thiamphenicol
| [Uses]
Demonstrates utility in fluorination.7 | [Uses]
Fluorinating agent. | [General Description]
GC analysis includes Et2NCF=CFCF3 (two isomers), both of which are active fluorinating agents. | [Synthesis]
N,N-diethyl-1,1,2,3,3,3-hexafluoropropylamine is prepared as follows: take 600-700 portions of dichloromethane, add 65-85 portions of diethylamine, lower the temperature to -5 ℃ to -25 ℃, pass 110 portions of -165 portions of hexafluoropropylene after the |
| Spectrum Detail | Back Directory | [Spectrum Detail]
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine(309-88-6)1HNMR
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine(309-88-6)19FNMR
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