| Identification | More | [Name]
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) | [CAS]
31011-57-1 | [Synonyms]
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
TITANIUM(IV) CHLORIDE TETRAHYDROFURAN COMPLEX (1:2)
TITANIUM TETRACHLORIDE BIS(TETRAHYDROFURAN) COMPLEX
TITANIUM TETRACHLORIDE TETRAHYDROFURAN COMPLEX
TRETRACHLOROBIS-(TETRAHYDROFURAN)-TITANIUM(IV)
TetrachlorobistetrahydrofurantitaniumIVminyellowxtl
Titanium(IV) chloride tetrahydrofuran complex
Tetrachlorobis(tetrahydrofurane)titanium(IV)
TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX
Tetrachlorobis(tetrahydrofuran)titanium(IV),min.97%
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97% | [Molecular Formula]
C8H16Cl4O2Ti | [MDL Number]
MFCD00077884 | [Molecular Weight]
333.89 | [MOL File]
31011-57-1.mol |
| Questions And Answer | Back Directory | [Preparation]
Tetrachlorobis(tetrahydrofuran)titanium(IV) can be obtained by reacting titanium tetrachloride and tetrahydrofuran in n-hexane (or dichloromethane). TiCl4 + 2 THF → TiCl4(THF)2 Because this reaction is violently exothermic, it is generally not carried out under solvent-free conditions. |
| Chemical Properties | Back Directory | [Melting point ]
126-128 °C(lit.) | [Fp ]
1 °F
| [storage temp. ]
2-8°C | [form ]
crystal | [color ]
yellow | [Water Solubility ]
Reacts with water | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4 | [InChIKey]
LXWBMENBONGPSB-UHFFFAOYSA-J | [SMILES]
[Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1 | [CAS DataBase Reference]
31011-57-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water.
R34:Causes burns.
R37:Irritating to the respiratory system. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2925 4.1/PG 2
| [WGK Germany ]
3
| [F ]
3-10 | [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
4.1B - Flammable solid hazardous materials | [Hazard Classifications]
Flam. Sol. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]:
2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3 | [Uses]
Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions. | [reaction suitability]
core: titanium
reagent type: Lewis acid
reagent type: catalyst |
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