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31571-14-9

31571-14-9 Structure

31571-14-9 Structure
IdentificationBack Directory
[Name]

ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME
[CAS]

31571-14-9
[Synonyms]

(1R,4S,E)
-3-(Hydroxyimino)
ISONITROSO-D-CAMPHOR
(1R,E)-(+)-CAMPHORQUINONE 3-OXIME
(1R,E)-(+)-2,3-BORNANEDIONE 3-OXIME
ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME
ANTI-(1R)-(+)-2,3-BORNANEDIONE 3-OXIME
anti-(1R)-(+)-Camphorquinone 3-Oxime >
ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME, 99 %
(1R,E)-(+)-2,3-Bornanedione 3-oxime, anti-(1R
anti-(1R)-(+)-Camphorquinone 3-Oxime
(2Z)-2-hydroxyimino-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one
Bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-, 3-oxime, (1R,3E,4S)-
(1R,E)-(+)-2,3-Bornanedione 3-oxime, anti-(1R)-(+)-Camphorquinone 3-oxime
[Molecular Formula]

C10H15NO2
[MDL Number]

MFCD00074848
[MOL File]

31571-14-9.mol
[Molecular Weight]

181.23
Chemical PropertiesBack Directory
[Melting point ]

153-156 °C(lit.)
[Boiling point ]

276.8±7.0 °C(Predicted)
[density ]

1.25±0.1 g/cm3(Predicted)
[refractive index ]

196 ° (C=1, EtOH)
[storage temp. ]

2-8°C
[form ]

powder to crystal
[pka]

9.35±0.60(Predicted)
[color ]

White to Orange to Green
[Optical Rotation]

[α]25/D +200°, c = 1 in ethanol
[Sensitive ]

Air Sensitive
[BRN ]

3200377
[InChI]

1S/C10H15NO2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11-13/h6,13H,4-5H2,1-3H3/b11-7-/t6-,10+/m1/s1
[InChIKey]

YRNPDSREMSMKIY-HAKKTOSXSA-N
[SMILES]

[H][C@@]12CC[C@@](C)(C(=O)\C1=N/O)C2(C)C
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[HS Code ]

2928.00.5000
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

(1R,E)-(+)-Camphorquinone 3-oxime can be used to prepare chiral camphor-oxazoline auxiliary, which is used to blend diastereoselectivity and isomer separability for the efficient synthesis of bicuculline, egenine, corlumine, and corytensine.
Spectrum DetailBack Directory
[Spectrum Detail]

ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME(31571-14-9)1HNMR
ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME(31571-14-9)FT-IR
ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME(31571-14-9)IR
ANTI-(1R)-(+)-CAMPHORQUINONE 3-OXIME(31571-14-9)Raman
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