| Identification | More | [Name]
D-Camphorsulfonic acid | [CAS]
3144-16-9 | [Synonyms]
(+)-10-CAMPHORSULFONIC ACID
(1S)-(+)-10-CAMPHORSULFONIC ACID
(1S,4R)-2-OXO-10-BORNANESULFONIC ACID
(1S)-BETA-CAMPHOR-10-SULFONIC ACID
(1S)-(+)-CAMPHOR-10-SULFONIC ACID
(1S)-CAMPHOR-10-SULFONIC ACID
(1S)-(+)-CAMPHOR-10-SULPHONIC ACID
2-Oxobornane-10-sulphonic acid
(+)-BETA-CAMPHORSULFONIC ACID
(+)-CAMPHOR-10-SULFONIC ACID
(+)-CAMPHOR-10-SULFONIC ACID (BETA)
CSA
D(+)-10-CAMPHORSULFONIC ACID
D-10-CAMPHORSULFONIC ACID
d-2-oxobornane-10-sulfonic acid
D-(+)-CAMPHOR-10-SULFONIC ACID
D-CAMPHOR-10-SULFONIC ACID
D(-)-CAMPHORSULFONIC ACID
D-(+)-CAMPHOR SULFONIC ACID
D-CAMPHORSULFONIC ACID | [EINECS(EC#)]
221-554-1 | [Molecular Formula]
C10H16O4S | [MDL Number]
MFCD00064157 | [Molecular Weight]
232.3 | [MOL File]
3144-16-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light beige powder | [Melting point ]
196-200 °C (dec.)(lit.)
| [alpha ]
22 º (589nm, c=20, H2O 25 ºC) | [Boiling point ]
344.46°C (rough estimate) | [density ]
1.2981 (rough estimate) | [refractive index ]
21.5 ° (C=5, H2O) | [storage temp. ]
2-8°C
| [solubility ]
Exhibit moderate solubility in HCCl. | [form ]
Crystalline Powder | [pka]
1.17±0.50(Predicted) | [color ]
White to off-white | [PH]
0.3 (200g/l, H2O) | [Stability:]
Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases. | [biological source]
human | [Optical Rotation]
[α]20/D +21.5±1°, c = 10% in H2O | [Water Solubility ]
SOLUBLE | [Sensitive ]
Hygroscopic | [Detection Methods]
T | [Merck ]
14,1734 | [BRN ]
2809675 | [InChI]
1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1 | [InChIKey]
MIOPJNTWMNEORI-GMSGAONNSA-N | [SMILES]
[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C | [CAS DataBase Reference]
3144-16-9(CAS DataBase Reference) | [EPA Substance Registry System]
3144-16-9(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H290-H314 | [Precautionary statements ]
P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
ED1550000
| [F ]
3-10 | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29147090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Met. Corr. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
white to light beige powder | [Uses]
Used as a resolving agent, and as a catalyst for coupling dipeptides. | [Definition]
ChEBI:(S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid. | [Purification Methods]
Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer. |
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