ChemicalBook--->CAS DataBase List--->3262-72-4

3262-72-4

3262-72-4 Structure

3262-72-4 Structure
IdentificationMore
[Name]

BOC-L-Serine
[CAS]

3262-72-4
[Synonyms]

BOC-L-SER
BOC-L-SERINE
BOC-L-SER-OH
BOC-SERINE
BOC-SERINE-OH
BOC-SER-OH
N-ALPHA-T-BOC-L-SERINE
N-ALPHA-TERT-BUTYLOXYCARBONYL-L-SERINE
N-BOC-L-SERINE
N-T-BUTOXYCARBONYL-L-SERINE
N-(TERT-BUTOXYCARBONYL)-L-SERINE
N-T-BOC-L-SERINE CRYSTALLINE
L-Serine, N-[(1,1-dimethylethoxy)carbonyl]-(9CI)
Boc-Ser-OH Synonyms:Boc-L-serine
N-ALPHA-T-BUTYLOXYCARBONYL-L-SERINE
BOC-L-PROLINOL LIQUID
N-[(1,1-DIMETHYLETHOXY)CARBONYL]-L-SERINE
N-Boc-L-serine, 98%(dry wt.), may cont. up to 10% water
BOC-L-SERINE extrapure
N-(tert-Butoxycarbonyl)-L-serine, Boc-L-serine
[EINECS(EC#)]

221-867-3
[Molecular Formula]

C8H15NO5
[MDL Number]

MFCD00037243
[Molecular Weight]

205.21
[MOL File]

3262-72-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to light brown powder
[Melting point ]

91 °C (dec.)(lit.)
[alpha ]

-7.5 º (c=2, water)
[Boiling point ]

385.1±37.0 °C(Predicted)
[density ]

1.240±0.06 g/cm3(Predicted)
[refractive index ]

-4 ° (C=1, AcOH)
[storage temp. ]

2-8°C
[solubility ]

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
[form ]

Powder
[pka]

3.62±0.10(Predicted)
[color ]

White
[Optical Rotation]

[α]20/D 3.5±0.5°, c = 2% in acetic acid
[Water Solubility ]

almost transparency
[BRN ]

2212252
[InChIKey]

FHOAKXBXYSJBGX-YFKPBYRVSA-N
[CAS DataBase Reference]

3262-72-4(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H319-H315
[Precautionary statements ]

P261-P271-P280
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[HS Code ]

29241990
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

N-BOC-O-Benzyl-L-serine-->Boc-Ser-OH-->Boc-Ser(Me)-OH-->(S)-2-(tert-Butoxycarbonylamino)-3-(tert-butyldiphenylsilyloxy)propanoic acid-->tert-Butyl (S)-1-(N-methoxy-N-methylcarbamoyl)-2-hydroxyethylcarbamate-->N-Boc-L-Ser-nhobn
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

BOC-L-Serine(3262-72-4).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light brown powder
[Uses]

Boc-Ser-OH may be used in the synthesis of the following:
  • 2-(N-Fmoc)-3-(N-Boc-N-methoxy)-diaminopropanoic acid (Fmoc: 9-fluorenylmethoxycarbonyl; Boc: t-butyloxycarbonyl)
  • Boc-Ser-Leu-OMe
  • cyclic peptide synthesis
  • benzylsulfonyl-D-Ser-Ser-4-amidinobenzylamide
[Uses]

Starting material for the synthesis of various a-amino acids via the b-lactone
[General Description]

Boc-Ser-OH is an amino acid derivative.
[reaction suitability]

reaction type: Boc solid-phase peptide synthesis
[Synthesis]

18.1g of L-serine, was added to 200m1 of 0.010mol/L sodium carbonate solution and dissolved with stirring, then 8g of (BoC)0 was added and reacted for 3 hours, then 8g of (BoC)0 was added and reacted for 5 hours, and finally 9g of (Boc)0 was added an
Spectrum DetailBack Directory
[Spectrum Detail]

BOC-L-Serine(3262-72-4)MS
BOC-L-Serine(3262-72-4)1HNMR
BOC-L-Serine(3262-72-4)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

BOC-L-Serine hydrate, tech., 93%(3262-72-4)
[Alfa Aesar]

N-Boc-L-serine, 98% (dry wt.), may cont. up to 10% water(3262-72-4)
[Sigma Aldrich]

3262-72-4(sigmaaldrich)
[TCI AMERICA]

N-(tert-Butoxycarbonyl)-L-serine,>96.0%(T)(3262-72-4)
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