| Identification | More | [Name]
10-Hydroxybenzo[h]quinoline | [CAS]
33155-90-7 | [Synonyms]
10-HYDROXYBENZO[H]QUINOLINE
benzo[h]quinolin-10-ol
HYDROXYBENZOQUINOLINE
10-Hydroxy-benzo[h]quinolin
10-HBQ
10-HYDROXY-BENZO[H]QUINOLIN(10-HBQ)
4-hydroxy-5-azaphenanthrene
10-Hydroxybenzohüquinoline, 98% | [EINECS(EC#)]
679-961-9 | [Molecular Formula]
C13H9NO | [MDL Number]
MFCD00142350 | [Molecular Weight]
195.22 | [MOL File]
33155-90-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
103-105°C | [Boiling point ]
420.6±18.0 °C(Predicted) | [density ]
1.307±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Soluble in acetone, chloroform and ethyl acetate. | [form ]
Solid | [pka]
8.03±0.30(Predicted) | [color ]
Yellow | [BRN ]
141770 | [InChI]
InChI=1S/C13H9NO/c15-11-5-1-3-9-6-7-10-4-2-8-14-13(10)12(9)11/h1-8,15H | [InChIKey]
KESRRRLHHXXBRW-UHFFFAOYSA-N | [SMILES]
N1C2C(=CC=C3C=CC=C(O)C3=2)C=CC=1 | [CAS DataBase Reference]
33155-90-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37:Wear suitable gloves . | [HS Code ]
29334900 |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow solid | [Uses]
5-Hydroxy-4-azaphenanthrene is used to detect boronic acids in reactions and boron containing compounds on solid support. 5-Hydroxy-4-azaphenanthrene is also used as a proton transfer-fluoresence probe to be applied to human serum albumin and beaver apomyoglobin. | [Synthesis]
10-Bromobenzo[h]quinoline (0.15 mmol, 39 mg) was added to an oven-dried screw-capped vial with carboxylic acid (0.3 mmol), silver carbonate (Ag-based, 0.165 mmol, 22 mg), potassium fluoride (0.15 mmol, 9 mg) and p-xylene (0.5 mL). The reaction mixture was stirred vigorously at 150 °C for 24 hours. After completion of the reaction, the mixture was cooled to room temperature and diluted with ethyl acetate. Subsequently, the solvent was removed by distillation under reduced pressure and the final product was purified by silica gel column chromatography. | [References]
[1] Tetrahedron Letters, 2016, vol. 57, # 7, p. 781 - 783
[2] Tetrahedron Letters, 2016, vol. 57, # 7, p. 781 - 783 |
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