| Identification | More | [Name]
CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE | [CAS]
33462-81-6 | [Synonyms]
Cyclopropyldiphenylsulfonium
cyclopropyl(diphenyl)sulfanium
Cyclopropyldiphenylsulfonium Fluobor
CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOR
Cyclopropyldiphenylsulfonium fluoborate.
CYCLOPROPYLDIPHENYLSULFONIUM TETRFLUOROBORATE
CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE
CYCLOPROPYLDIPHENYLSULPHONIUM TETRAFLUOROBORATE
Cyclopropyl(diphenyl)sulfanium,tetrafluoroborate
Cyclopropyldiphenylsulfonium Tetrafluoroborate >
Cyclopropyldiphenyl sulfonium tetrafluoroborate,98%
Sulfonium, cyclopropyldiphenyl-, tetrafluoroborate(1-) | [EINECS(EC#)]
251-530-6 | [Molecular Formula]
C15H15BF4S | [MDL Number]
MFCD00011873 | [Molecular Weight]
314.15 | [MOL File]
33462-81-6.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE FINE CRYSTALLINE POWDER | [Melting point ]
136-138 °C(lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
a suspension in THF, DME, DMSO, MeCN | [form ]
powder to crystal | [color ]
White to Almost white | [BRN ]
4172245 | [InChI]
InChI=1S/C15H15S.BF4/c1-3-7-13(8-4-1)16(15-11-12-15)14-9-5-2-6-10-14;2-1(3,4)5/h1-10,15H,11-12H2;/q+1;-1 | [InChIKey]
DWEYKSWKFYZEGZ-UHFFFAOYSA-N | [SMILES]
[S+](C1C=CC=CC=1)(C1=CC=CC=C1)C1CC1.[B-](F)(F)(F)F | [CAS DataBase Reference]
33462-81-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
1759 | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
2931900090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE FINE CRYSTALLINE POWDER | [Uses]
CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE is used as a versatile C3 building block; reagent for the spiroannulation of carbonyl compounds.
| [Synthesis]
Cyclopropyldiphenylsulfonium Tetrafluoroborate's synthesis:
| [References]
[1] Journal of Organic Chemistry, 2009, vol. 74, # 3, p. 1304 - 1313
[2] Patent: WO2017/83867, 2017, A1. Location in patent: Paragraph 00272; 00273
[3] Journal of the American Chemical Society, 1973, vol. 95, p. 5298 - 5307 |
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