| Identification | More | [Name]
9-Anthraldehyde oxime | [CAS]
34810-13-4 | [Synonyms]
9-ANTHRALDEHYDE OXIME
9-ANTHRALDOXIME
AKOS B004031
9-Anthraldehyde oxime, predominantly syn
9-ANTHRALDEHYDE OXIME, 99%, PREDOMINANTL Y SYN | [EINECS(EC#)]
625-998-0 | [Molecular Formula]
C15H11NO | [MDL Number]
MFCD00012252 | [Molecular Weight]
221.25 | [MOL File]
34810-13-4.mol |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
|
| Hazard Information | Back Directory | [Uses]
9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)]. | [General Description]
Gallium triflate catalyzed dehydration of 9-anthraldehyde oxime to nitrile is reported. | [Synthesis]
9-Anthraldehyde oxime was first synthesized by Hinkel and co-authors in 1935 (m.p. 186–187 °C). In repeating the preparation of the same compound by Fieser and Hartwell used a different procedure that afforded the desired compound in 93% yield with a different melting point of 165 °C.[1]
| [References]
[1] S. M. Ahmed, P. Quadrelli, Faiq H S Hussain. “9-Anthraldehyde oxime: a synthetic tool for variable applications.” Monatshefte für Chemie - Chemical Monthly 570 1 (2020): 1643–1658.
|
|
|