ChemicalBook--->CAS DataBase List--->3497-00-5

3497-00-5

3497-00-5 Structure

3497-00-5 Structure
IdentificationMore
[Name]

PHENYLTHIOPHOSPHONIC DICHLORIDE
[CAS]

3497-00-5
[Synonyms]

AURORA KA-1408
BENZENE PHOSPHORUS THIODICHLORIDE
Benzene phosphorus thiodichloride,Phenyl phosphorus thiodichloride
DICHLOROPHENYL PHOSPHINE SULFIDE
PHENYLPHOSPHONOTHIOIC DICHLORIDE
PHENYL THIONO PHOSPHONYL CHLORIDE
PHENYLTHIOPHOSPHONIC DICHLORIDE
dichloro(phenyl)phosphinesulphide
Phenyl phosphorus thiodichloride
phenyl-phosphonothioicdichlorid
Phenylphosphonothionodichloridate
Phenylphosphonothioyl dichloride
phenylphosphonothioyldichloride
phenylphosphorusthiodichloride
Phenylthionophosphonic dichloride
phenylthionophosphonicdichloride
Phenylthiophosphonyl dichloride
phenylthiophosphonyldichloride
Phosphine sulfide, dichlorophenyl-
Phosphonodichloridothioic acid, phenyl-
[EINECS(EC#)]

222-494-9
[Molecular Formula]

C6H5Cl2PS
[MDL Number]

MFCD00004916
[Molecular Weight]

211.05
[MOL File]

3497-00-5.mol
Chemical PropertiesBack Directory
[Melting point ]

76-77 °C
[Boiling point ]

270 °C
[density ]

1,4 g/cm3
[refractive index ]

1.6178-1.6182
[Fp ]

118℃
[form ]

clear liquid
[color ]

Colorless to Light orange to Yellow
[Water Solubility ]

1.522g/L(23 ºC)
[InChI]

1S/C6H5Cl2PS/c7-9(8,10)6-4-2-1-3-5-6/h1-5H
[InChIKey]

SXIWNIQDOJKDGB-UHFFFAOYSA-N
[SMILES]

ClP(Cl)(=S)c1ccccc1
[CAS DataBase Reference]

3497-00-5(CAS DataBase Reference)
[EPA Substance Registry System]

Phosphonothioic dichloride, P-phenyl- (3497-00-5)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314-H290
[Precautionary statements ]

P501-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

2799
[WGK Germany ]

WGK 3
[TSCA ]

TSCA listed
[HS Code ]

2931.90.6000
[HazardClass ]

8
[PackingGroup ]

II
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Met. Corr. 1
Skin Corr. 1B
[Safety Profile]

A corrosive. When heated to decomposition it emits toxic vapors of SOx and POx.
[Hazardous Substances Data]

3497-00-5(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

Colorless liquid with unpleasant acrid pungent odor. Corrodes metals slowly.
[Reactivity Profile]

PHENYLPHOSPHORUS THIODICHLORIDE(3497-00-5) is water reactive. Incompatible with strong oxidizing agents, alcohols, amines, alkali. Contact with active metals generates flammable hydrogen gas. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
[Air & Water Reactions]

Flammable. Decomposes to give hydrochloric acid in water, although this reaction is slow. The reaction becomes vigorous if the water is hot.
[Health Hazard]

CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.
[Fire Hazard]

EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.
[Uses]

Phenylthiophosphonic dichloride is a thiophosphonate and has been used to prepare high-refractive-index materials.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

benzene phosphorus thiodichloride(3497-00-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

PHENYLTHIOPHOSPHONIC DICHLORIDE(3497-00-5)MS
PHENYLTHIOPHOSPHONIC DICHLORIDE(3497-00-5)1HNMR
PHENYLTHIOPHOSPHONIC DICHLORIDE(3497-00-5)13CNMR
PHENYLTHIOPHOSPHONIC DICHLORIDE(3497-00-5)IR1
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