ChemicalBook--->CAS DataBase List--->354-32-5

354-32-5

354-32-5 Structure

354-32-5 Structure
IdentificationMore
[Name]

TRIFLUOROACETYL CHLORIDE
[CAS]

354-32-5
[Synonyms]

TRIFLUOROACETYL CHLORIDE
Acetyl chloride, trifluoro-
perfluoroacetylchloride
trifluoro-acetylchlorid
TRIFLUOROACETYL CHLORIDE CYL. WITH 800
Trifluoroacetylchloride97%
Trifluoracetylchlorid
Trifluoroacetic acid chloride
[EINECS(EC#)]

206-556-2
[Molecular Formula]

C2ClF3O
[MDL Number]

MFCD00039307
[Molecular Weight]

132.47
[MOL File]

354-32-5.mol
Chemical PropertiesBack Directory
[Melting point ]

−146 °C(lit.)
[Boiling point ]

−27 °C(lit.)
[density ]

1,335 g/cm3
[vapor density ]

4.6 (vs air)
[vapor pressure ]

546.6kPa at 25℃
[Fp ]

-58.1±25.9℃
[BRN ]

1098994
[Henry's Law Constant]

2.0×10-2 mol/(m3Pa) at 25℃, Mirabel et al. (1996)
[InChI]

InChI=1S/C2ClF3O/c3-1(7)2(4,5)6
[InChIKey]

PNQBEPDZQUOCNY-UHFFFAOYSA-N
[SMILES]

C(Cl)(C(F)(F)F)=O
[LogP]

0.79 at 25℃
[CAS DataBase Reference]

354-32-5(CAS DataBase Reference)
[EPA Substance Registry System]

Trifluoroacetyl chloride (354-32-5)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H314-H335
[Precautionary statements ]

P261-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R14:Reacts violently with water.
R35:Causes severe burns.
R37:Irritating to the respiratory system.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3057 2.3
[WGK Germany ]

2
[RTECS ]

AO7150000
[F ]

4.5-19-21
[Hazard Note ]

Corrosive
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

2.3
[Safety Profile]

Corrosive to skin, eyes, and materials. When heated to decomposition it emits very toxic fumes of Fand Cl-. See also FLUORIDES and CHLORIDES.
[Hazardous Substances Data]

354-32-5(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

A colorless gas. Shipped as a liquid under own vapor pressure. Contact with the unconfined liquid may frostbite unprotected skin. Very toxic by inhalation and may severely irritate skin, eyes, and mucous membranes. Under prolonged exposure to fire or heat the containers may rupture violently and rocket.
[Reactivity Profile]

TRIFLUOROACETYL CHLORIDE(354-32-5) is incompatible with strong oxidizing agents, alcohols, amines, alkalis. Reacts vigorously with amines and alkalis. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
[Air & Water Reactions]

Reacts avidly with water and with moisture in the air to give fumes of hydrogen chloride, a water-soluble toxic gas.
[Health Hazard]

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Vapors are extremely irritating and corrosive. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.
[Fire Hazard]

Some may burn but none ignite readily. Vapors from liquefied gas are initially heavier than air and spread along ground. Some of these materials may react violently with water. Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.
[Uses]

Widely used in medicine, pesticides, organic intermediate and fine chemical.
[Definition]

ChEBI: Trifluoroacetyl chloride is an acyl chloride. It is functionally related to a trifluoroacetic acid.
[Flammability and Explosibility]

Notclassified
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

trifluoroacetyl chloride(354-32-5).msds
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

354-32-5(sigmaaldrich)
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