| Identification | Back Directory | [Name]
2,4-Dichlorobenzothiazole | [CAS]
3622-30-8 | [Synonyms]
IFLAB-BB F1910-0008
2,4-Dichlorbenzothiazol
2,4-DICHLOROBENZOTHIAZOLE
Benzothiazole, 2,4-dichloro-
2,4-Dichlorobenzo[d]thiazole
2,4-DICHLORO-1,3-BENZOTHIAZOLE
Benzothiazole, 2,4-dichloro- (7CI,8CI,9CI)
sulfuric acid [[3-hydroxy-1-oxo-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)-2-mercapto-2-oxanyl]pent-4-enyl]amino] ester | [EINECS(EC#)]
222-821-5 | [Molecular Formula]
C7H3Cl2NS | [MDL Number]
MFCD00127716 | [MOL File]
3622-30-8.mol | [Molecular Weight]
204.08 |
| Chemical Properties | Back Directory | [Melting point ]
96-97 °C | [Boiling point ]
286.8±13.0 °C(Predicted) | [density ]
1.567±0.06 g/cm3(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [pka]
-2.02±0.10(Predicted) | [Appearance]
Light yellow to orange Solid |
| Hazard Information | Back Directory | [Chemical Properties]
Pale yellow solid | [Synthesis]
Step B: 4-Chlorobenzo[d]thiazol-2-amine (4.78 g, 25.8 mmol) and copper(II) chloride (4.16 g, 31 mmol) were dissolved in acetonitrile (25 mL), followed by tert-butyl nitrite (4.61 mL, 38.8 mmol) at room temperature. The reaction mixture was heated to 60 °C and maintained for 30 min. Upon completion of the reaction, the solvent was removed by rotary evaporation. The residue was suspended in water and the solid product was collected by filtration and dried to give 2,4-dichlorobenzo[d]thiazole (5.3 g, 81% yield). Mass spectrometry analysis showed a m/z of 205.9 [M + H]+. | [References]
[1] Chemistry - A European Journal, 2018, vol. 24, # 55, p. 14622 - 14626
[2] Patent: WO2013/101974, 2013, A1. Location in patent: Paragraph 00586; 00588
[3] Patent: US9617268, 2017, B2. Location in patent: Page/Page column 321; 322
[4] Gazzetta Chimica Italiana, 1964, vol. 94, p. 372 - 381
[5] Chemistry and Biodiversity, 2011, vol. 8, # 2, p. 253 - 265 |
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