ChemicalBook--->CAS DataBase List--->36335-67-8

36335-67-8

36335-67-8 Structure

36335-67-8 Structure
IdentificationBack Directory
[Name]

BUTAMIFOS
[CAS]

36335-67-8
[Synonyms]

s28
s2846
tufler
h26905
kremart
CREMART
Cremarat
BUTAMIFOS
metacrefos
hercules26905
BUTAMIFOS STANDARD
Butamifos Solution, 100ppm
Butamifos Reference Material
O-ETHYLO-(6-NITRO-M-TOLYL)-S-BUTYLPHOSPHORAMIDOTHIOATE
O-Ethyl O-6-nitro-m-tolyl sec-butylphosphoramidothioate
o-ethylo-(3-methyl-6-nitrophenyl)n-sec-butylphosphorothioamidate
n-(sec-butyl)-phosphoramidothioicacio-ethylo-(6-nitro-m-tolyl)ester
O-Ethyl O-(5-methyl-2-nitrophenyl) N-sec-butylphosphorothionoamidate
(1-methylpropyl)-phosphoramidothioicacio-ethylo-(5-methyl-2-nitropheny
o-ethyl-o-(5-methyl-2-nitrophenyl)(1-methylpropyl)phosphoramidothioate
N-(sec-Butyl)phosphoramidothioic acid O-ethyl O-(5-methyl-2-nitrophenyl)
Phosphoramidothioic acid, N-(sec-butyl)-, O-ethyl O-(6-nitro-m-tolyl) ester
Phosphoramidothioic acid, N-(1-methylpropyl)-, O-ethyl O-(5-methyl-2-nitrophenyl) ester
[Molecular Formula]

C13H21N2O4PS
[MDL Number]

MFCD00210251
[MOL File]

36335-67-8.mol
[Molecular Weight]

332.36
Chemical PropertiesBack Directory
[Melting point ]

<25 °C
[Boiling point ]

422.1±55.0 °C(Predicted)
[density ]

1.223±0.06 g/cm3(Predicted)
[storage temp. ]

0-6°C
[form ]

neat
[pka]

-0.51±0.70(Predicted)
[BRN ]

2165895
[EPA Substance Registry System]

Phosphoramidothioic acid, (1-methylpropyl)-, O-ethyl O-(5-methyl-2-nitrophenyl) ester (36335-67-8)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-50/53
[Safety Statements ]

61
[RIDADR ]

UN 3082 9 / PGIII
[WGK Germany ]

3
[HS Code ]

29299090
Raw materials And Preparation ProductsBack Directory
Hazard InformationBack Directory
[Uses]

Butamifos (S-2846) is an organophosphoramidate herbicide used to control annual weeds with low toxicity to mammals. Butamifos acts on the growing points of susceptible plants, causing severe radial enlargement of the affected tissues[1].
[Definition]

ChEBI: Butamifos is a C-nitro compound.
[Metabolic pathway]

In water, butamifos undergoes photoinduced intramolecular oxygen transfer from the nitro group to the P=?S moiety, resulting in the formation of the nitrosooxon derivative. Through the successive reduction of the nitroso group to hydroxyamino and amino groups, as well as oxidation to the nitro group, the nitrosooxon derivative is finally photodegraded to various polar compounds. The isomer of butamifos is photodegraded more slowly than butamifos in air, and its main photodegradation pathway in water is oxidation of the arylmethyl group to form a corresponding carboxylic acid derivative.
[References]

[1] SUMIDA S, et al. Chlorella as a model system to study herbicidal mode of action and its application to a new herbicide, O-ethyl-O-(3-methyl-6-nitrophenyl)-N-sec-butyl phosphorothioamidate (S-2846)[M]. 1974.
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