| Identification | Back Directory | [Name]
2-(BROMOVINYL)TRIMETHYLSILANE | [CAS]
41309-43-7 | [Synonyms]
(2-BROMOVINYL)TRIMETHYLSILANE(CIS
(E)-2-(Trimethylsilyl)vinyl bromide
[(E)-2-BroMovinyl](triMethyl)silane
(E)-(2-Bromoethenyl)trimethylsilane
(E)-(2-Bromoethenyl)trimethyl-silane
(2-BroMovinyl)triMethylsilane approx.
trans-1-Bromo-2-(trimethylsilyl)ethene
Silane, [(1E)-2-bromoethenyl]trimethyl-
(2-BROMOVINYL)TRIMETHYLSILANE(CIS+TRANS)
(2-BroMovinyl)triMethylsilane approx. 90% trans, 98%
(2-BROMOVINYL)TRIMETHYLSILANE , PRED OMINANTLY TRANS
(2-BROMOVINYL)TRIMETHYLSILANE, 98%, PRED OMINANTLY TRANS
β-(Trimethylsilyl)vinyl bromide, 1-Bromo-2-(trimethylsilyl)ethylene | [Molecular Formula]
C5H11BrSi | [MDL Number]
MFCD00040824 | [MOL File]
41309-43-7.mol | [Molecular Weight]
179.13 |
| Chemical Properties | Back Directory | [Boiling point ]
50-51 °C52 mm Hg(lit.)
| [density ]
1.167 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.466(lit.)
| [Fp ]
85 °F
| [storage temp. ]
2-8°C
| [form ]
liquid | [Specific Gravity]
1.167 | [Hydrolytic Sensitivity]
3: reacts with aqueous base | [BRN ]
1700085 | [InChI]
InChI=1S/C5H11BrSi/c1-7(2,3)5-4-6/h4-5H,1-3H3/b5-4+ | [InChIKey]
FKXCNOSKBLGEMQ-SNAWJCMRSA-N | [SMILES]
[Si](/C=C/Br)(C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
10-36/37/38 | [Safety Statements ]
26 | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [F ]
10 | [TSCA ]
No | [HazardClass ]
3.2 | [PackingGroup ]
III | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Synthesis]
HBr gas was drummed into a mixture of trimethylmethylsilylacetylene (20 g, 0.2 mol) and benzoyl peroxide (145 mg, 0.6 mmol, 0.3 mol%) cooled in an ice bath for 15 min (the reaction progress was monitored by 1HNMR). The reaction mixture was diluted with et |
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