| Identification | More | [Name]
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE | [CAS]
433-06-7 | [Synonyms]
2,2,2-TRIFLUOROETHYL 4-METHYLBENZENESULFONATE
2,2,2-TRIFLUOROETHYL-4-TOLUENESULFONATE
2,2,2-TRIFLUOROETHYL 4-TOLUENESULPHONATE
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE
2,2,2-TRIFLUOROETHYL P-TOLUENESULPHONATE
2,2,2-TRIFLUOROETHYL TOSYLATE
P-TOLUENESULFONIC ACID 2,2,2-TRIFLUOROETHYL ESTER
TRIFLUORETHYLTOSYLATE
TRIFLUOROETHANOL TOSYLATE
2,2,2-trifluoro-ethano4-methylbenzenesulfonate
Ethanol, 2,2,2-trifluoro-, p-toluenesulfonate
p-Toluenesulphonic acid 2,2,2-trifluoroethyl ester
2,2,2-Trifluoroethyl 4-toluenesulphonate 98%
2,2,2-Trifluoroethyl4-toluenesulphonate98%
4-Toluenesulfonic acid 2,2,2,-trifluoroethyl ester
2,2,2-Trifluoroethyl p-toluenesulfonate, 98+%
4-Methylbenzenesulfonic acid 2,2,2-trifluoroethyl ester
p-Methylbenzenesulfonic acid 2,2,2-trifluoromethyl
Trifluoroethyltosylate | [EINECS(EC#)]
207-085-5 | [Molecular Formula]
C9H9F3O3S | [MDL Number]
MFCD00000443 | [Molecular Weight]
254.23 | [MOL File]
433-06-7.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE CRYSTALLINE SOLID | [Melting point ]
36-38 °C(lit.)
| [Boiling point ]
87-92 °C0.1 mm Hg(lit.)
| [density ]
1 g/cm3 | [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Sparingly), Methanol (Sparingly) | [form ]
Solid | [color ]
White to Off-White | [Sensitive ]
Moisture Sensitive | [BRN ]
2699394 | [Stability:]
Hygroscopic | [InChI]
1S/C9H9F3O3S/c1-7-2-4-8(5-3-7)16(13,14)15-6-9(10,11)12/h2-5H,6H2,1H3 | [InChIKey]
IGKCQDUYZULGBM-UHFFFAOYSA-N | [SMILES]
Cc1ccc(cc1)S(=O)(=O)OCC(F)(F)F | [CAS DataBase Reference]
433-06-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethanol, 2,2,2-trifluoro-, 4-methylbenzenesulfonate(433-06-7) | [EPA Substance Registry System]
433-06-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29049090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE CRYSTALLINE SOLID | [Uses]
2,2,2-Trifluoroethyl Tosylate is a trifluoroethylation agent used in the preparation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile. | [Synthesis]
2,2,2-Trifluoroethyl p-Toluenesulfonate is easily prepared by treating 2,2,2-trifluoroethanol with p-Toluenesulfonyl Chloride in pyridine or in aqueous acetone containing NaOH.
| [Precautions]
Quite stable; can be handled without any special technique and stored at room temperature; use in a fume hood.
|
| Spectrum Detail | Back Directory | [Spectrum Detail]
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)MS
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)1HNMR
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)13CNMR
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)IR1
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)IR2
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE(433-06-7)Raman
|
|
|