| Identification | More | [Name]
1-ADAMANTYL ISOCYANATE | [CAS]
4411-25-0 | [Synonyms]
1-ADAMANTYL ISOCYANATE
RARECHEM AQ TC 1023
1-Admantyl Isocyanate
1-Isocyanatoadamantane
1-ADAMANTYL ISOCYANATE 98%
1-isocyantoadamantane
Adamantane-1-yl isocyanate | [Molecular Formula]
C11H15NO | [MDL Number]
MFCD00134405 | [Molecular Weight]
177.24 | [MOL File]
4411-25-0.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
144-146 °C (lit.) | [Boiling point ]
309.18°C (rough estimate) | [density ]
1.0290 (rough estimate) | [refractive index ]
1.5302 (estimate) | [solubility ]
soluble in Acetone | [form ]
Powder | [color ]
White | [InChI]
InChI=1S/C11H15NO/c13-7-12-11-4-8-1-9(5-11)3-10(2-8)6-11/h8-10H,1-6H2 | [InChIKey]
VBHCPGFCIQDXGZ-UHFFFAOYSA-N | [SMILES]
C12(N=C=O)CC3CC(CC(C3)C1)C2 | [CAS DataBase Reference]
4411-25-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
2206 | [WGK Germany ]
3
| [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29291090 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
1-Adamantyl isocyanate may be used in the preparation of:
- adamantyl-functionalized nanoparticles, via thiol-isocyanate reaction of thiol-modified nanoparticles1 4-[3-(aryl or -cycloalkyl)ureido]butyryl compound
- 4-(3-adamantan-1-yl-ureido)butyric acid, via reaction with 4-aminobutanoic acid in DMF
- 4-(3-adamantan-1-yl-ureido)butyryloxy compound
- 12-(3-adamantan-1-yl-ureido) dodecanoic acid (AUDA)
- adamantyl-phenylsulfonamide ureas
- 1-adamantan-1-yl-3-(hydroxyalkyl)ureas, via reaction with with hydroxyalkylamines
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 55, p. 4282, 1990 DOI: 10.1021/jo00301a014 | [General Description]
1-Adamantyl isocyanate is an isocyanate derivative. | [Purification Methods]
Recrystallise the isocyanate from n-hexane and sublime it. Irritant. [Stetter & Wulff Chem Ber 95 2302 1962.] |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|