| Identification | More | [Name]
TRANS-4-METHYL-BETA-NITROSTYRENE | [CAS]
5153-68-4 | [Synonyms]
1-(4-METHYLPHENYL)-2-NITROETHENE
1-(4-METHYLPHENYL)-2-NITROETHYLENE
1-METHYL-4-(2-NITROVINYL)BENZENE
1-(P-TOLYL)-2-NITROETHYLENE
4'-METHYL-BETA-NITROSTYRENE
4-METHYL-OMEGA-NITROSTYRENE
4-METHYL-W-NITROSTYRENE
TRANS-4-METHYL-BETA-NITROSTYRENE
1-(4-Methylphenyl)-2-nitroethylene~1-(p-Tolyl)-2-nitroethylene
trans-4-methyl-á-nitrostyrene
trans-4-methyl-β-nitrostyrene
trans-4-Methyl-^b-nitrostyrene, 98% | [Molecular Formula]
C9H9NO2 | [MDL Number]
MFCD00024828 | [Molecular Weight]
163.17 | [MOL File]
5153-68-4.mol |
| Chemical Properties | Back Directory | [Melting point ]
102-104 °C (lit.) | [Boiling point ]
275.0±9.0 °C(Predicted) | [density ]
1.141±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C | [form ]
solid | [Appearance]
Off-white to light yellow Solid | [Water Solubility ]
Sparingly Soluble in water (0.070 g/L) (25°C). | [BRN ]
1864209 | [InChI]
1S/C9H9NO2/c1-8-2-4-9(5-3-8)6-7-10(11)12/h2-7H,1H3/b7-6+ | [InChIKey]
JSPNBERPFLONRX-VOTSOKGWSA-N | [SMILES]
[H]\C(=C(\[H])[N+]([O-])=O)c1ccc(C)cc1 | [CAS DataBase Reference]
5153-68-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
trans-4-Methyl-β-nitrostyrene may be used as a reagent in the synthesis of N-benzylpyrrolomorphinans. It is also used as an organic intermediate for pharmaceutical. | [General Description]
trans-4-Methyl-β-nitrostyrene ((E)-1-methyl-4-(2-nitrovinyl)benzene) is a nitrolefin. Its asymmetric Michael addition with benzaldehyde in the presence of silylated pyrrolidine catalyst has been reported. Its hydrogenation in the presence of Pd(II) complexes of (Z)-2-((quinolin-3-ylimino)methyl)phenol as catalyst has been studied. |
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Alfa Aesar
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400-6106006 |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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https://www.sigmaaldrich.cn |
| Company Name: |
3A Chemicals
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400-668-9898 |
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www.3achem.com |
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