| Identification | More | [Name]
4-(Dimethylamino)benzophenone | [CAS]
530-44-9 | [Synonyms]
4-(DIMETHYLAMINO)BENZOPHENONE
4-(N,N-DIMETHYLAMINO)BENZOPHENONE
P-(DIMETHYLAMINO)BENZOPHENONE
(4-Dimethylamino-phenyl)-phenyl-methanone
[4-(Dimethylamino)phenyl](phenyl)methanone
[4-(dimethylamino)phenyl]phenyl-methanon
[4-(Dimethylamino)phenyl]phenylmethanone
4-Dimethylaminobenzophenon
Benzenamine,N,N-dimethyl-4-(phenylmethanone)-
Benzophenone, 4-(dimethylamino)-
Methanone,[4-(dimethylamino)phenyl]phenyl-
p-Benzoyl-N,N-dimethylaniline
4-BENZOYL-N,N-DIMETHYLANILINE | [EINECS(EC#)]
208-478-4 | [Molecular Formula]
C15H15NO | [MDL Number]
MFCD00008311 | [Molecular Weight]
225.29 | [MOL File]
530-44-9.mol |
| Chemical Properties | Back Directory | [Appearance]
YELLOW CRYSTALLINE POWDER OR CRYSTALS | [Melting point ]
88-90 °C(lit.)
| [Boiling point ]
250 °C / 15mmHg | [density ]
1.0463 (rough estimate) | [refractive index ]
1.5200 (estimate) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
powder to crystal | [pka]
2.12±0.12(Predicted) | [color ]
White to Light yellow to Green | [Water Solubility ]
insoluble | [Merck ]
14,3233 | [InChI]
1S/C15H15NO/c1-16(2)14-10-8-13(9-11-14)15(17)12-6-4-3-5-7-12/h3-11H,1-2H3 | [InChIKey]
BEUGBYXJXMVRFO-UHFFFAOYSA-N | [SMILES]
CN(C)c1ccc(cc1)C(=O)c2ccccc2 | [CAS DataBase Reference]
530-44-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Methanone, [4-(dimethylamino)phenyl]phenyl-(530-44-9) | [EPA Substance Registry System]
530-44-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29223900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
YELLOW CRYSTALLINE POWDER OR CRYSTALS | [Uses]
4-(Dimethylamino)benzophenone is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. | [Synthesis Reference(s)]
Synthesis, p. 544, 1986 DOI: 10.1055/s-1986-31696
Tetrahedron Letters, 34, p. 7595, 1993 DOI: 10.1016/S0040-4039(00)60409-4 | [Purification Methods]
Crystallise the pale green p-dimethylaminobenzophenone from EtOH. Dissolve 100g in 600mL of boiling EtOH, add 5g of charcoal, cool, isolate the solid by centrifugation and similarly wash the pale crystals with ice-cold EtOH. When filtered by suction, EtOH solution remains on the crystals and turns deep green in air. Dry it in a vacuum and store it in the dark. The hydrazone has m 128-130o and forms a ketyl with potassium. [Hurd & Webb Org Synth Coll Vol I 217 1941, Beilstein 14 H 82, 14 I 288, 14 III 218, 14 IV 248.] |
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