ChemicalBook--->CAS DataBase List--->536-75-4

536-75-4

536-75-4 Structure

536-75-4 Structure
IdentificationMore
[Name]

4-Ethylpyridine
[CAS]

536-75-4
[Synonyms]

4-ETHANOLPYRIDINE
4-ETHYLPYRIDINE
ETHYLPYRIDINE
GAMMA-ETHYLPYRIDINE
4-ethvlpvridine
4-ethyl-pyridin
Pyridine, 4-ethyl-
g-Ethylpyridine
[EINECS(EC#)]

208-646-7
[Molecular Formula]

C7H9N
[MDL Number]

MFCD00006450
[Molecular Weight]

107.15
[MOL File]

536-75-4.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to yellowish liquid
[Melting point ]

-91 °C
[Boiling point ]

168 °C(lit.)
[density ]

0.942 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.501(lit.)
[Fp ]

118 °F
[storage temp. ]

Flammables area
[solubility ]

107g/l
[form ]

Liquid
[pka]

pK1:5.87(+1) (25°C)
[color ]

Clear colorless to yellow
[PH]

10 (100g/l, H2O, 20℃)
[Water Solubility ]

34 g/L
[Merck ]

14,3849
[BRN ]

106481
[Dielectric constant]

10.98
[InChI]

1S/C7H9N/c1-2-7-3-5-8-6-4-7/h3-6H,2H2,1H3
[Contact allergens]

4-Ethyl-pyridine is used as a monomer in polymer chemistry
[InChIKey]

VJXRKZJMGVSXPX-UHFFFAOYSA-N
[SMILES]

CCc1ccncc1
[LogP]

1.650
[CAS DataBase Reference]

536-75-4(CAS DataBase Reference)
[NIST Chemistry Reference]

4-(C2H5)-pyridine(536-75-4)
[EPA Substance Registry System]

536-75-4(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to yellowish liquid
[Uses]

4-Ethyl pyridine is used as a monomer in polymer chemistry.
[Production Methods]

4-Ethylpyridine is produced by Wolff-Kishner reduction of 4-Acetylpyridine.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 22, p. 694, 1957 DOI: 10.1021/jo01357a607
Tetrahedron Letters, 26, p. 275, 1985 DOI: 10.1016/S0040-4039(01)80795-4
[General Description]

4-Ethylpyridine undergoes metal-ligand interaction with Zn-porphyrin which can be studied by mass spectrometry.
[Purification Methods]

Dry 4-ethylpyridine with BaO, and fractionally distil it. Also purified by converting to the picrate, recrystalising and the free base is regenerated and distilled. [Beilstein 20/6 V 10.]
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2924 3/PG 3
[WGK Germany ]

3
[F ]

8
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29333999
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

ZINC
[Preparation Products]

2-Amino-4-ethylpyridine-->1-Pyridin-4-yl-ethylamine-->2-Ethylpyridine-->4,4'-Bis(methoxycarbonly)-2,2'-bipyridine-->4-Ethyl-2-pyridinecarbonitrile
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Ethylpyridine(536-75-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4-Ethylpyridine(536-75-4)MS
4-Ethylpyridine(536-75-4)1HNMR
4-Ethylpyridine(536-75-4)13CNMR
4-Ethylpyridine(536-75-4)IR1
4-Ethylpyridine(536-75-4)Raman
4-Ethylpyridine(536-75-4)ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Ethylpyridine, 98%(536-75-4)
[Alfa Aesar]

4-Ethylpyridine, 98%(536-75-4)
[Sigma Aldrich]

536-75-4(sigmaaldrich)
[TCI AMERICA]

4-Ethylpyridine,>98.0%(GC)(536-75-4)
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