ChemicalBook--->CAS DataBase List--->59080-45-4

59080-45-4

59080-45-4 Structure

59080-45-4 Structure
IdentificationMore
[Name]

HEXYL-BETA-D-GLUCOPYRANOSIDE
[CAS]

59080-45-4
[Synonyms]

N-HEXYL-BETA-D-GLC
1-Hexyl β-D-Glucoside
n-Hexyl-β-D-Glucoside
HEXYL-BETA-D-GLUCOSIDE
HEXYL B-D-GLUCOPYRANOSIDE
Hexyl β-D-glucopyranoside
HEXYL-SS-D-GLUCOPYRANOSIDE
b-D-Glucopyranoside, hexyl
N-HEXYL B-D-GLUCOPYRANOSIDE
n-Hexyl β-D-Glucopyranoside
Hexyl-Beta-D-glucopryanoside
HEXYL-BETA-D-GLUCOPYRANOSIDE
N-HEXYL-BETA-D-GLUCOPYRANOSIDE
Hexyl-β-D-glucopyranoside solution
Hexyl-β-D-glucoside 200 mM solution
HEXYL-BETA-D-GLUCOPYRANOSIDE USP/EP/BP
Hexyl--D-glucoside 200 mM Solution
Detergent Screening Solution 01/Fluka kit no 66317
[EINECS(EC#)]

1533716-785-6
[Molecular Formula]

C12H24O6
[MDL Number]

MFCD00063305
[Molecular Weight]

264.32
[MOL File]

59080-45-4.mol
Chemical PropertiesBack Directory
[Appearance]

White Crystalline Solid
[Melting point ]

84-86°C
[Boiling point ]

432.3±45.0 °C(Predicted)
[density ]

1.23±0.1 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

Acetone, Ethanol, Water
[form ]

Solid
[pka]

12.96±0.70(Predicted)
[color ]

White Crystalline
[Optical Rotation]

[α]20/D 33±2°, c = 5% in H2O
[Usage]

A mild nonionic detergent
[BRN ]

83239
[CAS DataBase Reference]

59080-45-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

3-9
[HS Code ]

29400090
Hazard InformationBack Directory
[Chemical Properties]

White Crystalline Solid
[Uses]

A mild nonionic detergent
[Uses]

A mild nonionic detergent.
[Synthesis]

β-D-Glucose

492-61-5

1-Hexanol

111-27-3

N-HEXYL-BETA-D-GLC

39824-11-8

In standard synthesis experiments, (2R,3R,4S,5S,6R)-6-(hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol and n-hexanol were used as starting materials for the preparation of the target compound (CAS:39824-11-8). This was done as follows: first, 18 mL of tertiary alcohol was mixed with 2 mL of aqueous solution containing 0.25 mol/L glucose as reaction medium. Subsequently, 60 mg of almond powder was added to the mixture as a catalyst. The reaction system was transferred to a 100 mL round-bottomed flask and the reaction was carried out in a constant temperature water bath at 50 °C with continuous oscillation at 180 r/min. During the reaction, 50 μL was sampled periodically and the reaction progress was monitored by high performance liquid chromatography (HPLC). For the synthesis of methyl-D-glucoside, 2 mL of methanol, 16 mL of acetonitrile mixed with 2 mL of aqueous solution containing 0.25 mol/L glucose was required as the reaction system.

[References]

[1] Chinese Journal of Catalysis, 2012, vol. 33, # 2-3, p. 275 - 280
[2] Chinese Journal of Catalysis, 2012, vol. 33, # 2-3, p. 275 - 280
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

59080-45-4(sigmaaldrich)
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