ChemicalBook--->CAS DataBase List--->6018-94-6

6018-94-6

6018-94-6 Structure

6018-94-6 Structure
IdentificationMore
[Name]

NICKEL OXALATE DIHYDRATE
[CAS]

6018-94-6
[Synonyms]

NICKEL(II) OXALATE
NICKEL(II) OXALATE DIHYDRATE
NICKEL OXALATE
NICKEL OXALATE DIHYDRATE
NICKEL OXALATE, HYDROUS
Nickel(II)oxalatedihydrate(99.998%-Ni)PURATREM
Nickel(II) oxalate dihydrate, 99.999% metals basis
NICKEL(II) OXALATE DIHYDRATE: 99.998%
Nickel oxalate (solids)
Nickel(II) oxalate hydrate, Puratronic, 99.9985% (metals basis)
[EINECS(EC#)]

208-933-7
[Molecular Formula]

C2H4NiO6
[MDL Number]

MFCD00167155
[Molecular Weight]

182.74
[MOL File]

6018-94-6.mol
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[solubility ]

insoluble in H2O; soluble in acid solutions,NH2OH 4
[form ]

Powder
[color ]

green-white
[Water Solubility ]

Soluble in acids. Insoluble in water
[Merck ]

14,6514
[Solubility Product Constant (Ksp)]

pKsp: 9.4
[Exposure limits]

NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
[Major Application]

battery manufacturing
[InChI]

1S/C2H2O4.Ni.2H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);;2*1H2/q;+2;;/p-2
[InChIKey]

VNYOIRCILMCTHO-UHFFFAOYSA-L
[SMILES]

O.O.O=C1O[Ni]OC1=O
[CAS DataBase Reference]

6018-94-6(CAS DataBase Reference)
Hazard InformationBack Directory
[Chemical Properties]

light green powder(s) [MER06]
[Uses]

It is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuffs.
[Uses]

Nickel oxalate is used for the production of nickel catalysts and magnetic materials.
[Preparation]

Nickel(II) oxalate precipitates as NiC2O4?2H2O when oxalic acid is added to nickel salt solutions. It is isomorphous with the oxalates of magnesium, zinc and iron(II), and has μeff=2.95 BM. When heated in vacuo it decomposes evolving water above 150° and carbon dioxide above 300° leaving finely divided nickel suitable for catalytic purposes or reacting to form the carbonyl. The oxalate dissolves in acids with decomposition and in ammonia with ammine formation.
[Production Methods]

Nickel Oxalate is produced as a greenish white crystalline dihydrate.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S9:Keep container in a well-ventilated place .
S7:Keep container tightly closed .
[RIDADR ]

UN3288
[WGK Germany ]

WGK 3
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 1A Inhalation
Skin Sens. 1
STOT RE 1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Nickel(II) oxalate dihydrate(6018-94-6)
[Sigma Aldrich]

6018-94-6(sigmaaldrich)
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