ChemicalBook--->CAS DataBase List--->60748-47-2

60748-47-2

60748-47-2 Structure

60748-47-2 Structure
IdentificationBack Directory
[Name]

Tris(dibenzylideneacetone)dipalladium
[CAS]

60748-47-2
[Synonyms]

PD(DBA)X
PD2(DBA)3
PD2DBA3 5G
Tris(dibenzylideneacetone)dipalladium
BIS(DIBENZYLIDENEACETONE)PALLADIUM(II)
TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0)
TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM (O)
Tris(dibenTris(dibenzylideneacetone)dipalladium
Tris(dibenzylideneacetone)dipalladium ISO 9001:2015 REACH
3,3,6,6-tetramethyl-9-(1,2,3,4-tetrahydroxybutyl)-4,5,7,9-t
3,3,6,6-tetramethyl-9-(1,2,3,4-tetrahydroxybutyl)-4,5,7,9-tetrahydro-2H-xanthene-1,8-dione
[Molecular Formula]

C51H42O3Pd2
[MDL Number]

MFCD00013310
[MOL File]

60748-47-2.mol
[Molecular Weight]

915.72
Chemical PropertiesBack Directory
[Melting point ]

152-155 °C(lit.)
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform (Sparingly, Sonicated), DMSO (Slightly, Sonicated), Methanol (Slightly, Sonicated)
[form ]

Solid
[color ]

Dark Red to Black
[InChI]

InChI=1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;
[InChIKey]

CYPYTURSJDMMMP-WVCUSYJESA-N
[SMILES]

C1(=CC=CC=C1)/C=C/C(/C=C/C1=CC=CC=C1)=O.C1(=CC=CC=C1)/C=C/C(=O)/C=C/C1=CC=CC=C1.C1(=CC=CC=C1)/C=C/C(=O)/C=C/C1=CC=CC=C1.[Pd].[Pd]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Safety Statements ]

24/25
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor.
[Synthesis]

Palladium acetate was dissolved in dichloromethane; dibenzylidene acetone was dissolved in anhydrous ethanol and toluene (1:1); a homemade redox resin was used to fill a two-stage 5L reactor; the palladium solution and the dibenzylidene acetone solution w
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