| Identification | More | [Name]
4-NITROBENZO-15-CROWN-5 | [CAS]
60835-69-0 | [Synonyms]
2,3-(4-NITROBENZO)-1,4,7,10,13-PENTAOXACYCLOPENTADEC-2-ENE
4'-NITROBENZO-15-CROWN-5
4-NITROBENZO-15-CROWN-5
4'-NITROBENZO-15-CROWN 5-ETHER
CROWN ETHER/4'-NITROBENZO-15-CROWN-5
NITROBENZO-15-CROWN-5
15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine
17-Nitro-2,3-benzo-1,4,7,10,13-pentaoxacyclopentadecen-2
CARBON DISULFIDE, REAGENTPLUS, >=99.9%, LOW BENZENE
4-Nitrobenzo-15-crown-5,99%
1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-nitro-
1,13-(4-Nitro-1,2-phenylene)-1,4,7,10,13-pentaoxatridecane
1,2-(1,4,7,10,13-Pentaoxatridecane-1,13-diyl)-4-nitrobenzene
15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin
16-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin | [Molecular Formula]
C14H19NO7 | [MDL Number]
MFCD00060713 | [Molecular Weight]
313.3 | [MOL File]
60835-69-0.mol |
| Chemical Properties | Back Directory | [Appearance]
LIGHT YELLOW GRANULAR POWDER | [Melting point ]
93-97 °C(lit.) | [Boiling point ]
453.11°C (rough estimate) | [density ]
1.191 | [refractive index ]
1.5230 (estimate) | [storage temp. ]
Store below +30°C. | [solubility ]
It is soluble in non-polar solvents. | [form ]
powder to crystal | [color ]
Light orange to Yellow to Green | [BRN ]
1598970 | [InChI]
InChI=1S/C14H19NO7/c16-15(17)12-1-2-13-14(11-12)22-10-8-20-6-4-18-3-5-19-7-9-21-13/h1-2,11H,3-10H2 | [InChIKey]
XIWRBQVYCZCEPG-UHFFFAOYSA-N | [SMILES]
O1C2=CC=C([N+]([O-])=O)C=C2OCCOCCOCCOCC1 | [CAS DataBase Reference]
60835-69-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P280a-P304+P340-P305+P351+P338-P405-P501a | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HazardClass ]
IRRITANT | [HS Code ]
29329990 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
LIGHT YELLOW GRANULAR POWDER | [Uses]
4-Nitrobenzo-15-crown-5 is a raw material used in synthesis as well as an intemediate in chemical syntheis and pharmaceutica intemediate. It is also used to separate cations, dissolve inorganic salts into organic solvents to perform naked anion chemistry, serve as phase transfer catalysts, and chiral crown ethers have been used to resolve racemic mixtures or separate isomers by chiral chromatography. | [Purification Methods]
Recrystallise the crown ether from EtOH, MeOH or *C6H6/hexane as for the 18-crown-6 compound below. It complexes with Na+, K+, NH4+, Ca2+, Mg2+ and Cd2+. The 1HNMR spectrum (CDCl3) has (ppm): 3.6-4.4 (m 16CH2), 6.8 (d 1H arom), 7.65 (d 1H arom), 7.80 (dd 1H arom Jab 9Hz and Jbc 3Hz) [Schmid et al. J Am Chem Soc 98 5198 1976, Kikukawa et al. Bull Chem Soc Jpn 50 2207 1977, Toke et al. Justus Liebigs Ann Chem 349 349, 761 1988, Lindner et al. Z Anal Chem 322 157 1985]. |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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