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611-21-2

611-21-2 Structure

611-21-2 Structure
IdentificationMore
[Name]

N-METHYL-O-TOLUIDINE
[CAS]

611-21-2
[Synonyms]

2-(METHYLAMINO)TOLUENE
2-METHYL-N-METHYLANILINE
N,2-DIMETHYLANILINE
N-METHYL-2-TOLUIDINE
N-METHYL-O-TOLUIDINE
2,N-Dimethylaniline
Benzenamine, N,2-dimethyl-
n,2-dimethyl-benzenamin
N,2-Dimethylbenzenamine
o-Toluidine, N-methyl-
N-Methyl-o-touidine
N-METHYL-ORTHO-TOLUIDINE
N-Methyl-o-t
N-Methyl-o-methylaniline
1-Methylamino-2-methylbenzene
N,6-Dimethylaniline
[EINECS(EC#)]

210-260-9
[Molecular Formula]

C8H11N
[MDL Number]

MFCD00025627
[Molecular Weight]

121.18
[MOL File]

611-21-2.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR YELLOW LIQUID
[Melting point ]

-10.08°C (estimate)
[Boiling point ]

207 °C
[density ]

0.97
[refractive index ]

1.562-1.565
[Fp ]

79.4 °C
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[Water Solubility ]

Practically insoluble in water
[form ]

clear liquid
[pka]

4.72±0.10(Predicted)
[color ]

White to Yellow to Green
[InChI]

InChI=1S/C8H11N/c1-7-5-3-4-6-8(7)9-2/h3-6,9H,1-2H3
[InChIKey]

GUAWMXYQZKVRCW-UHFFFAOYSA-N
[SMILES]

C1(NC)=CC=CC=C1C
[CAS DataBase Reference]

611-21-2(CAS DataBase Reference)
[Storage Precautions]

Air sensitive
[EPA Substance Registry System]

Benzenamine, N,2-dimethyl- (611-21-2)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R33:Danger of cumulative effects.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

1711
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HazardClass ]

6.1(a)
[PackingGroup ]

II
[HS Code ]

2921490090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Hexane-->Formaldehyde-->Sodium borohydride-->o-Toluidine-->1H-Benzotriazole
[Preparation Products]

N,N,2-Trimethylbenzenamine-->Quinoline-->Phenazinium, 2-methyl-3-(methylamino)-5-phenyl-7-(phenylamino)-, chloride-->Phenazinium, 3-(ethylamino)-2,8-dimethyl-7-(methylamino)-5-phenyl-, chloride
Hazard InformationBack Directory
[Chemical Properties]

Clear liquid, darkening on storage
[Uses]

Reactant for:
  • Palladium-catalyzed coupling reactions
  • Palladium-catalyzed amination of bromoindazoles
[Synthesis Reference(s)]

Tetrahedron, 42, p. 4027, 1986 DOI: 10.1016/S0040-4020(01)87558-X
[General Description]

N-Methyl-o-toluidine can be synthesized by reacting o-toluidine and benzotriazole.
Spectrum DetailBack Directory
[Spectrum Detail]

N-METHYL-O-TOLUIDINE(611-21-2)MS
N-METHYL-O-TOLUIDINE(611-21-2)1HNMR
N-METHYL-O-TOLUIDINE(611-21-2)13CNMR
N-METHYL-O-TOLUIDINE(611-21-2)IR1
N-METHYL-O-TOLUIDINE(611-21-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Methyl-o-toluidine, 98%(611-21-2)
[Sigma Aldrich]

611-21-2(sigmaaldrich)
[TCI AMERICA]

N-Methyl-o-toluidine,>95.0%(GC)(611-21-2)
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