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62086-04-8

62086-04-8 Structure

62086-04-8 Structure
IdentificationMore
[Name]

TIN(II) TRIFLUOROMETHANESULFONATE
[CAS]

62086-04-8
[Synonyms]

STANNOUS TRIFLUOROMETHANESULFONATE
TIN(II) TRIFLATE
TIN(II) TRIFLUOROMETHANESULFONATE
TIN(II) TRIFLUOROMETHANESULPHONATE
TIN TRIFLATE
TIN TRIFLUOROMETHANESULFONATE
TRIFLUOROMETHANESULFONIC ACID TIN(2) SALT
TRIFLUOROMETHANESULFONIC ACID TIN(II) SALT
Stannous triflate~Tin(II) triflate
Tin(II) trifluoromethanesulphonate, tech.
Zinc(II)trifluoromethanesulfonate
Tin(II)trifluoromethanesulfonate,99%(Tintriflate)
Stannous trifluoromethanesulfonate, Tin(II) triflate
Bis(trifluoromethanesulfonic acid) tin(II) salt
Bis(trifluoromethanesulfonic acid)tin(II) salt
Tin(II)bis(trifluoromethanesulfonate)
Trifluoromethanesulfonic acid tin(II)
[Molecular Formula]

C2F6O6S2Sn
[MDL Number]

MFCD00191251
[Molecular Weight]

416.85
[MOL File]

62086-04-8.mol
Chemical PropertiesBack Directory
[Appearance]

White to yellowish powder
[Melting point ]

≥300 °C (lit.)
[storage temp. ]

Refrigerator
[form ]

Powder
[color ]

White to yellow
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Moisture Sensitive
[Stability:]

hygroscopic
[InChI]

1S/2CHF3O3S.Sn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
[InChIKey]

RBGLVWCAGPITBS-UHFFFAOYSA-L
[SMILES]

FC(F)(F)S(=O)(=O)O[SnH2]OS(=O)(=O)C(F)(F)F
[CAS DataBase Reference]

62086-04-8(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)Exclamation Mark (GHS07)Corrosion (GHS05)
GHS06,GHS07,GHS05
[Signal word ]

Danger
[Hazard statements ]

H301+H311+H331-H315-H319-H314-H302-H312-H331
[Precautionary statements ]

P280h-P304+P340-P311a-P501a-P280-P305+P351+P338-P310-P261-P264-P270-P271-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 3146 6.1/PG 3
[WGK Germany ]

3
[F ]

1-10
[Hazard Note ]

Corrosive
[TSCA ]

No
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29049090
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Description]

Mild Lewis acid, primarily used to generate tin(II) enolates for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements; addition of tin(II) acetylides to aldehydes; asymmetric allylation of aldehydes.
[Chemical Properties]

White to yellowish powder
[Uses]

Tin(II) trifluoromethanesulfonate is a mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements, Horner-Wadsworth-Emmons reactions, asymmetric [3 + 2] cycloaddition, ring opening reactions and Friedel-Crafts reactions.
[reaction suitability]

core: tin
reagent type: catalyst
[storage]

Moisture and air sensitive; all handling and storage should be done under nitrogen.
Spectrum DetailBack Directory
[Spectrum Detail]

TIN(II) TRIFLUOROMETHANESULFONATE(62086-04-8)IR1
TIN(II) TRIFLUOROMETHANESULFONATE(62086-04-8)IR2
TIN(II) TRIFLUOROMETHANESULFONATE(62086-04-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tin(II) trifluoromethanesulfonate, 98%(62086-04-8)
[Alfa Aesar]

Tin(II) trifluoromethanesulfonate, 97%(62086-04-8)
[Sigma Aldrich]

62086-04-8(sigmaaldrich)
[TCI AMERICA]

Tin(II) Trifluoromethanesulfonate,>90.0%(T)(62086-04-8)
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