ChemicalBook--->CAS DataBase List--->623-50-7

623-50-7

623-50-7 Structure

623-50-7 Structure
IdentificationMore
[Name]

Ethyl glycolate
[CAS]

623-50-7
[Synonyms]

DIETHYL GLYCOLATE
ETHYL GLYCOLATE
ETHYL HYDROXYACETATE
GLYCOLIC ACID ETHYL ESTER
HYDROXYACETIC ACID ETHYL ESTER
2-hydroxy-aceticacidethylester
HOCH2COOC2H5
hydroxy-aceticaciethylester
ethyl glycollate
GlycolicAcidEthylEster=Ethylhydroxyacetate=
ETHYL2-HYDROXYACETATE
Acetic acid, hydroxy-, ethyl ester
Hydroxyacetic acid ethyl
[EINECS(EC#)]

210-798-4
[Molecular Formula]

C4H8O3
[MDL Number]

MFCD00021970
[Molecular Weight]

104.1
[MOL File]

623-50-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

>300 °C
[Boiling point ]

158-159 °C (lit.)
[density ]

1.1 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.419(lit.)
[Fp ]

143 °F
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Chloroform, Methanol (Slightly)
[form ]

Liquid
[pka]

13.14±0.10(Predicted)
[color ]

Colorless
[Odor]

Peculiar ethereal, weedy-winey odour, often classified as "Spearmint-like".
[Water Solubility ]

It is very soluble in water, alcohols, acetone, acetates, slightly soluble in ethyl ether, sparingly soluble in hydrocarbon solvents, polymerization occurs above 50 C.
[InChI]

1S/C4H8O3/c1-2-7-4(6)3-5/h5H,2-3H2,1H3
[InChIKey]

ZANNOFHADGWOLI-UHFFFAOYSA-N
[SMILES]

CCOC(=O)CO
[CAS DataBase Reference]

623-50-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Acetic acid, hydroxy-, ethyl ester(623-50-7)
[EPA Substance Registry System]

623-50-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

1993
[WGK Germany ]

3
[RTECS ]

MC5410000
[TSCA ]

Yes
[HazardClass ]

3.2
[PackingGroup ]

III
[HS Code ]

29181990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl oxalate-->Ethyl diazoacetate-->Glycolonitrile
[Preparation Products]

Furo[2,3-b]pyridine-2-carboxylic acid, 3-amino-, ethyl ester (9CI)-->Fluroxypyr-->1,3-Dioxolane-4-methanol-->Ethyl nitroacetate-->(2,4-dinitro-phenoxy)-acetic acid ethyl ester-->3H-1,2,4-Triazole-3-thione, 2,4-dihydro-5-(hydroxymethyl)-4-methyl- (9CI)-->2-Trifluoromethanesulfonyloxyaceticacidethylester-->ethyl 3-aMino-6-broMo-1-benzofuran-2-carboxylate-->N-Cyclohexylglycine-->Acetic acid, (2,3-dichlorophenoxy)-, ethyl ester-->ethyl 2-((4-methoxybenzyl)oxy)acetate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ethyl glycolate(623-50-7).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Ethyl glycolate, is an important building block for the preparation of agrochemicals and medicinal compounds. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff. It is also used in synthetic chemistry, discovery process and R&D. It also can be used as solvents.
[Application]

Ethyl glycollate is an important building block for the preparation of medicinal compounds and agrochemicals. It may be used:
  • as starting reagent in the synthesis of 2-ferrocenylfuran;
  • as substrate during the polycondensation of α-hydroxy acids by enzymes and polyethylene glycol (PEG)-modified enzymes;
  • in the synthesis of poly(PDL-GA) copolymers, via enzymatic catalysis.
[Production Methods]

The corresponding acid occurs in unripe Grapes. Ethyl glycolate is produced from Ethylene glycol by oxidation to Glycoiiic acid, followed by esterification.
[General Description]

Ethyl glycollate is an ester. Microwave spectra of ethyl glycollate and its deuterated species has been reported.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl glycolate(623-50-7)MS
Ethyl glycolate(623-50-7)1HNMR
Ethyl glycolate(623-50-7)13CNMR
Ethyl glycolate(623-50-7)IR1
Ethyl glycolate(623-50-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl glycolate, 95%(623-50-7)
[Alfa Aesar]

Ethyl glycolate, 95%(623-50-7)
[Sigma Aldrich]

623-50-7(sigmaaldrich)
[TCI AMERICA]

Ethyl Glycolate,>98.0%(GC)(623-50-7)
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