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626-27-7

626-27-7 Structure

626-27-7 Structure
IdentificationMore
[Name]

HEPTANOIC ANHYDRIDE
[CAS]

626-27-7
[Synonyms]

ENANTHIC ANHYDRIDE
HEPTANOIC ANHYDRIDE
N-HEPTANOIC ANHYDRIDE
OENANTHIC ANHYDRIDE
heptanoicacid,anhydride
heptanoicacidanhydride
Heptanoyl anhydride
n-Heptanoic acid anhydride
HEPTANOIC ANHYDRIDE 99%
Enanthic acid anhydride
heptylic anhydride
Enanthic anhydride, Oenanthic anhydride
Bisenanthic anhydride
Bisheptanoic anhydride
Diheptanoic anhydride
[EINECS(EC#)]

210-940-5
[Molecular Formula]

C14H26O3
[MDL Number]

MFCD00009536
[Molecular Weight]

242.35
[MOL File]

626-27-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear light yellow liquid
[Melting point ]

-12 °C
[Boiling point ]

278-282 °C
[density ]

0.917
[vapor pressure ]

0.22Pa at 25℃
[refractive index ]

1.432-1.434
[Fp ]

110 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Liquid
[color ]

Clear light yellow
[InChI]

InChI=1S/C14H26O3/c1-3-5-7-9-11-13(15)17-14(16)12-10-8-6-4-2/h3-12H2,1-2H3
[InChIKey]

DAPZDAPTZFJZTO-UHFFFAOYSA-N
[SMILES]

O(C(=O)CCCCCC)C(=O)CCCCCC
[LogP]

5.58 at 25℃
[CAS DataBase Reference]

626-27-7(CAS DataBase Reference)
[EPA Substance Registry System]

Heptanoic acid, anhydride (626-27-7)
Questions And Answer(Q&A)Back Directory
[Uses]

Heptanic anhydride can be used in organic synthesis.

Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

1760
[TSCA ]

TSCA listed
[REACH Registrations]

Inactive
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29159000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Heptanoic acid-->2-Chloropyridine-N-oxide-->Heptanoyl chloride
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow liquid
[Preparation]

To a flask containing 15.8 gm (0.2 mole) of dry pyridine and 25 ml of dry benzene is rapidly added with stirring 14.8 gm (0.1 mole) of heptanoyl chloride. The reaction is only slightly exothermic and then 13.0 gm (0.1 mole) of heptanoic acid is added dropwise (5 min) causing the temperature to rise to 60-65°C. After stirring for 10 min, the solid (pyridinium hydrochloride) is quickly filtered, washed twice with 25 ml portions of dry benzene, the benzene washings concentrated under reduced pressure, and the residue distilled to afford 19-20 gm (78-83%), b.p. 155-162°C (12 mm Hg), or 170-173°C (15 min).
Preparation of Heptanoic Anhydride
[Flammability and Explosibility]

Nonflammable
[Safety]

HEPTANOIC ANHYDRIDE is irritating and corrosive; contact may cause severe skin burns and eye damage, and may also trigger allergic skin reactions.
Spectrum DetailBack Directory
[Spectrum Detail]

HEPTANOIC ANHYDRIDE(626-27-7)MS
HEPTANOIC ANHYDRIDE(626-27-7)1HNMR
HEPTANOIC ANHYDRIDE(626-27-7)13CNMR
HEPTANOIC ANHYDRIDE(626-27-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Heptanoic anhydride, 99%(626-27-7)
[TCI AMERICA]

Heptanoic Anhydride,>95.0%(T)(626-27-7)
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