| Identification | More | [Name]
4-Mercaptophenol | [CAS]
637-89-8 | [Synonyms]
4-HYDROXYBENZENETHIOL
4-HYDROXYTHIOPHENOL
4-MERCAPTOPHENOL
P-MERCAPTOPHENOL
4-Sulfanylphenol
Hydroquinone, monothio-
monothio-hydroquinon
Monothiohydroquinone
Phenol, 4-mercapto-
Phenol, p-mercapto-
p-Hydroxythiophenol
Thiohydroquinone
USAF B-57
usafb-57
Hydroxythiophenol,94%
4-MERCAPTOPHENOL, TECH., 90%
4-HYDROXYTHIOPHENOL 99%
4-Hydroxythiophenol,97%
PARA-THIOPHENOL
PARA-MERCAPTOPHENOL | [EINECS(EC#)]
211-307-6 | [Molecular Formula]
C6H6OS | [MDL Number]
MFCD00004850 | [Molecular Weight]
126.18 | [MOL File]
637-89-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to light yellow solid or liquid | [Melting point ]
33-35 °C(lit.)
| [Boiling point ]
149-150 °C25 mm Hg(lit.)
| [density ]
1.255 | [refractive index ]
1.5101 (estimate) | [Fp ]
>230 °F
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Liquid or Low Melting Solid | [pka]
6.82±0.10(Predicted) | [color ]
Clear colorless to light yellow | [Stability:]
Stability Air sensitive. Incompatible with oxidizing agents. | [Water Solubility ]
soluble | [Sensitive ]
Air Sensitive | [BRN ]
2039306 | [LogP]
1.690 (est) | [CAS DataBase Reference]
637-89-8(CAS DataBase Reference) | [NIST Chemistry Reference]
4-Mercaptophenol(637-89-8) | [Storage Precautions]
Air sensitive;Store under nitrogen | [EPA Substance Registry System]
637-89-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi,C,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
2811 | [WGK Germany ]
3
| [RTECS ]
MX7175000
| [F ]
10-13-23 | [Hazard Note ]
Harmful/Irritant | [HazardClass ]
8 | [HazardClass ]
AIR SENSITIVE, IRRITANT-HARMFUL, STENCH | [PackingGroup ]
III | [HS Code ]
29309090 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to light yellow solid or liquid | [Uses]
4-Mercaptophenol (MPH) has been used to study the adsorption of MPH on silver coated polystyrene nanospheres by time-dependent surface-enhanced Raman scattering (SERS) spectroscopy.
4-Mercaptophenol may be used in the preparation of silylated monomer, which was employed for the synthesis of hyperbranched poly(ester-imide). 4-Mercaptophenol (H-4MP) reacts with metal tert-butoxides ([M(OBut)4]) to yield the following Group 4 phenoxy-thiols:
- [(HOBut)(4MP)3M(μ-4MP)]2, where M = Ti, Zr, Hf
- [(py)2M(4MP)], where M = Ti, Zr; py = pyridine
- [(py)(4MP)3Hf(μ-4MP)]2
4-Mercaptophenol may be used in the synthesis of the following:
- poly(ethersulfide)s via silylation followed by polycondensation with 2,6-dichloropyridine or 3,6-dichloropyridazine
- 2,6-di-tertiarybutyl-4-mercaptophenol via Friedel-Craft′s alkylation with tert-butyl chloride in presence of a lewis acid
| [Uses]
4-Mercaptophenol was used as a resin monomer in the study of the different gold nanocrystal core-resin shell structures. | [General Description]
The density function theory calculations were performed to infer the IR and Raman spectra for 4-mercaptophenol molecule. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Maya High Purity Chemicals
|
| Telephone: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
|