ChemicalBook--->CAS DataBase List--->67883-79-8

67883-79-8

67883-79-8 Structure

67883-79-8 Structure
IdentificationMore
[Name]

cis-3-Hexenyl tiglate
[CAS]

67883-79-8
[Synonyms]

CIS-3-HEXEN-1-YL TIGLATE
CIS-3-HEXENYL TIGLATE
FEMA 3931
HEXENYL-CIS-3-TIGLATE
TIGLIC ACID CIS-3-HEXEN-1-YL ESTER
(e,z)-2-methyl-2-butenoicacid3-hexenylester
2-methyl-,3-hexenylester,(e,z)-2-butenoicaci
2-methyl-,3-hexenylester,(E,Z)-2-Butenoicacid
cis-3-hexenyl-2-methyl-trans-2-butenoate
cis-Hex-3-ene-1-yltrans-2-methyl-2-butenoate
(Z)-3-hexenyl 2-methylcrotonate
CIS-3-HEXENYL TIGLATE 97+%
2-Butenoic acid, 2-methyl-, (3Z)-3-hexenyl ester, (2E)-
(Z)-3-Hexenyl-2-methylcrotonat
Tiglic acid 3-hexen-1-yl ester
(E)-2-Methyl-2-butenoic acid (Z)-3-hexenyl ester
(Z)-3-Hexene-1-ol (2E)-2-methyl-2-butenoate
2-Methylcrotonic acid (Z)-3-hexenyl ester
Tiglic acid (Z)-3-hexenyl ester
[EINECS(EC#)]

267-554-5
[Molecular Formula]

C11H18O2
[MDL Number]

MFCD00036528
[Molecular Weight]

182.26
[MOL File]

67883-79-8.mol
Chemical PropertiesBack Directory
[Boiling point ]

105 °C5 mm Hg(lit.)
[density ]

0.951 g/mL at 25 °C(lit.)
[FEMA ]

3931
[refractive index ]

n20/D 1.46(lit.)
[Fp ]

204 °F
[storage temp. ]

Store at room temperature
[solubility ]

Almost insoluble in water, soluble in alcohol and oils
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Odor]

at 10.00 % in propylene glycol. green vegetable green banana earthy cortex herbal
[Odor Type]

green
[JECFA Number]

1277
[Cosmetics Ingredients Functions]

PERFUMING
[LogP]

4.20
[CAS DataBase Reference]

67883-79-8(CAS DataBase Reference)
[EPA Substance Registry System]

67883-79-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R38:Irritating to the skin.
[Safety Statements ]

S37:Wear suitable gloves .
[WGK Germany ]

2
[RTECS ]

EM9253500
[TSCA ]

TSCA listed
[HS Code ]

29161900
Hazard InformationBack Directory
[Chemical Properties]

(Z)-3-Hexenyl (E)-2-methyl 2-butenoate has a fresh, green, floral, fruity odor
[Uses]

Cis-3-Hexenyl tiglate finds a little use in the reconstruction of various essential oils, and as part of the topnote complex in modern, green-herbaceous fragrances and as a fresh topnote element in florals and bouquets. Its aroma differs substantially from that of the saturated ester, which is not at all green but very warm-herbaceous and winey, resembling notes in Roman Chamomile oil. It is, therefore, doubtful if the subject ester will find much use in flavour compositions except as a trace component modifier in certain fruit and vegetable flavour compositions.
[Production Methods]

Cis-3-Hexenyl tiglate is produced from cis-3-Hexenol and Tiglic acid by direct esterification.
[Aroma threshold values]

Aroma characteristics at 1.0%: green, earthy vegetative with mushroom and radish nuances
[Taste threshold values]

Taste characteristics at 1 to 5 ppm: green vegetative mushroom with herbaceous and fatty nuances.
Spectrum DetailBack Directory
[Spectrum Detail]

cis-3-Hexenyl tiglate(67883-79-8)1HNMR
cis-3-Hexenyl tiglate(67883-79-8)13CNMR
cis-3-Hexenyl tiglate(67883-79-8)IR1
cis-3-Hexenyl tiglate(67883-79-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

67883-79-8(sigmaaldrich)
[TCI AMERICA]

Tiglic Acid cis-3-Hexen-1-yl Ester,>98.0%(GC)(67883-79-8)
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