ChemicalBook--->CAS DataBase List--->683-18-1

683-18-1

683-18-1 Structure

683-18-1 Structure
IdentificationMore
[Name]

Dibutyltin dichloride
[CAS]

683-18-1
[Synonyms]

DIBUTYLDICHLOROSTANNANE
DIBUTYLDICHLOROTIN
DIBUTYLDICHLOROTIN(+4)
DIBUTYLTIN(+4)DICHLORIDE
DIBUTYLTIN DICHLORIDE
DIBUTYLTIN(IV) DICHLORIDE
DI-N-BUTYLDICHLOROTIN
DI-N-BUTYLTIN DICHLORIDE
chloriddi-n-butylcinicity
chloriddi-n-butylcinicity(czech)
dibutyldichloro-stannan
dibutylstanniumdichloride
dibutyl-tidichloride
dibutyltinchloride
dichlorodibutylstannane
dichlorodibutyltin
di-n-butyl-zinn-dichlorid
Stannane, dibutyldichloro
Di-n-butyltin dichloride, 97+%
Di-n-butyltindichloride,95+%
[EINECS(EC#)]

211-670-0
[Molecular Formula]

C8H18Cl2Sn
[MDL Number]

MFCD00000518
[Molecular Weight]

303.84
[MOL File]

683-18-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to beige crystalline low melting mass
[Melting point ]

39 °C
[Boiling point ]

135 °C10 mm Hg(lit.)
[density ]

1.4
[vapor pressure ]

0.0016 hPa (25 °C)
[refractive index ]

1.4991
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[solubility ]

0.32g/l
[form ]

Crystalline
[color ]

White
[Specific Gravity]

1.36
[Water Solubility ]

320 mg/L, hydrolises in hot water
[Sensitive ]

Moisture Sensitive
[BRN ]

3535484
[Exposure limits]

ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
[InChI]

1S/2C4H9.2ClH.Sn/c2*1-3-4-2;;;/h2*1,3-4H2,2H3;2*1H;/q;;;;+2/p-2
[InChIKey]

RJGHQTVXGKYATR-UHFFFAOYSA-L
[SMILES]

CCCC[Sn](Cl)(Cl)CCCC
[CAS DataBase Reference]

683-18-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Di-n-butyltindichloride(683-18-1)
[EPA Substance Registry System]

683-18-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R25:Toxic if swallowed.
R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R63:Possible risk of harm to the unborn child.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
[RIDADR ]

UN 2928 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

WH7100000
[F ]

10-21
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29310095
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 2 Inhalation
Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Muta. 2
Repr. 1B
Skin Corr. 1B
Skin Sens. 1
STOT RE 1 Oral
STOT SE 1 Oral
[Safety Profile]

Poison by ingestion, intravenous, and intraperitoneal routes. Moderately toxic by skin contact. A severe skin and eye irritant. Experimental reproductive effects. Mutation data reported. See also TIN COMPOUNDS. Combustible when exposed to heat or flame. A dangerous material; emits highly toxic fumes of HCl; wdl react with water or steam to produce heat and toxic fumes; can react vigorously with oxidizing materials. To Poison by ingestion, intravenous, and intraperitoneal routes. Moderately toxic by skin contact. A severe skin and eye irritant. Experimental reproductive effects. Mutation data reported. See also TIN COMPOUNDS. Combustible when exposed to heat or flame. A dangerous material; emits highly toxic fumes of HCl; wdl react with water or steam to produce heat and toxic fumes; can react vigorously with oxidizing materials. Tofight fue, use water, foam, CO2, dry chemical.
[Hazardous Substances Data]

683-18-1(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 50 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

butyltricyclohexylstannane-->di-n-butyltin-->Butyltin trichloride-->Tricyclohexyltin chloride-->Tin tetrachloride-->Tin-->Tributyltin chloride-->Tetrabutyltin-->Tri-n-butyltin acetate-->1-Iodobutane
[Preparation Products]

Dibutyltin oxide-->3'-Fluorobutyrophenone-->3'-Methylbutyrophenone-->1,2-Diphenyl-butan-1-one-->m-Chlorobutyrophenone-->Dibutylbis(pentafluorophenyl)stannane-->Dibutyldiethoxystannane
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Di-n-Butyldichlorotin(683-18-1).msds
Hazard InformationBack Directory
[Chemical Properties]

white to beige crystalline low melting mass
[Uses]

Organotin intermediate.Di-n-butyltin dichloride is used as an organotin intermediate. It serves as heat and light stabilizer for polyvinyl chloride plastics. It is also used in the preparation of methyl 2-(methoxycarbonylmethyl)-5-iodobenzene by reacting with 2,5-diiodobenzoic acid. It acts as an esterification catalyst and a veterinary vermicide and tapeworm remedy. Further, it is used as ion exchange agent, process regulators and processing aids.
[Preparation]

Dibutyltin dichloride is manufactured from crude tetrabutyltin and tin tetrachloride and is usually catalysed with aluminium trichloride (Blunden & Evans, 1989; Gaver, 1997; Thoonen et al., 2001)
Spectrum DetailBack Directory
[Spectrum Detail]

Dibutyltin dichloride(683-18-1)MS
Dibutyltin dichloride(683-18-1)1HNMR
Dibutyltin dichloride(683-18-1)13CNMR
Dibutyltin dichloride(683-18-1)IR1
Dibutyltin dichloride(683-18-1)IR2
Dibutyltin dichloride(683-18-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Dibutyltin dichloride, 97%(683-18-1)
[Alfa Aesar]

Di-n-butyltin dichloride, 96%(683-18-1)
[Sigma Aldrich]

683-18-1(sigmaaldrich)
[TCI AMERICA]

Dibutyltin Dichloride,>97.0%(T)(683-18-1)
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