| Identification | More | [Name]
Diethyl fluoromalonate | [CAS]
685-88-1 | [Synonyms]
2-FLUORO-MALONIC ACID DIETHYL ESTER
DIETHYL 2-FLUOROMALONATE
DIETHYL FLUOROMALONATE
FLUOROMALONIC ACID DIETHYL ESTER
diethylfluoropropanedioate
Ethyl fluoromalonate
fluoro-malonicacidiethylester
fluoro-propanedioicacidiethylester
Malonic acid, fluoro-, diethyl ester
Monofluoromalonic acid diethyl ester
Propanedioic acid, fluoro-, diethyl ester
DiethylfluoroMalonate96%
Diethylfluoromalonate,97%
fluoropropanedioic acid diethyl ester
Diethyl 2-fluoromalonate 97%
Diethyl2-fluoromalonate97% | [EINECS(EC#)]
211-684-7 | [Molecular Formula]
C7H11FO4 | [MDL Number]
MFCD00009139 | [Molecular Weight]
178.16 | [MOL File]
685-88-1.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO PALE YELLOW LIQUID | [Boiling point ]
121-122 °C30 mm Hg(lit.)
| [density ]
1.129 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.407(lit.)
| [Fp ]
144 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Liquid | [pka]
10.40±0.46(Predicted) | [color ]
Clear colorless to pale yellow | [Specific Gravity]
1.129 | [BRN ]
1775686 | [InChI]
InChI=1S/C7H11FO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3 | [InChIKey]
GOWQBFVDZPZZFA-UHFFFAOYSA-N | [SMILES]
C(OCC)(=O)C(F)C(OCC)=O | [CAS DataBase Reference]
685-88-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Diethyl fluoromalonate(685-88-1) |
| Safety Data | Back Directory | [Hazard Codes ]
C,T | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
OO1670000
| [F ]
19 | [Hazard Note ]
Corrosive | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29171900 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO PALE YELLOW LIQUID | [Uses]
The kinetic parameters of diethyl fluoromalonate in hemolysates were used to study carboxylesterase activities in complex systems. | [General Description]
The reaction of diethyl fluoromalonate with electron-poor and electron-rich, sterically hindered and unhindered aryl bromides and chlorides were studied. | [Synthesis]
In a 250m1 round bottom flask, 5g of sodium carbonate, 10g of cobalt octacarbonyl, 72ml (57g, 1. 25mol) of ethanol and 53ml (61g, 0. 5mol) of ethyl chloroacetate were added, and CO2 was passed through the gas at a flow rate of 50m1/min for 6h, and the |
|
|