ChemicalBook--->CAS DataBase List--->68858-21-9

68858-21-9

68858-21-9 Structure

68858-21-9 Structure
IdentificationMore
[Name]

4-(Hydroxymethyl)phenoxyacetic acid
[CAS]

68858-21-9
[Synonyms]

4-(HYDROXYMETHYL)PHENOXYACETIC ACID
HMP
HMPA
HMPA LINKER
HMP LINKER
HPA LINKER
P-(HYDROXYMETHYL)PHENOXYACETIC ACID
HMP LINKER,4-(HYDROXYMETHYL) PHENOXYACETIC ACID
HMP Linker Synonyms:4-(Hydroxymethyl)Phenoxyacetic Acid
Fmoc-SCAL-linker (safety-catch linker for solid phase synthesis)
4-(HYDROXYMETHYL)PHENOXYACETIC ACID HMP LINKER 99+%
HMP LINKER, 99% MIN.
4-(Hydroxymethyl)phenoxyacetic acid, 98+%
[EINECS(EC#)]

677-017-0
[Molecular Formula]

C9H10O4
[MDL Number]

MFCD00057827
[Molecular Weight]

182.17
[MOL File]

68858-21-9.mol
Chemical PropertiesBack Directory
[Melting point ]

112-114 °C
[Boiling point ]

378.3±22.0 °C(Predicted)
[density ]

1.316±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
[form ]

Crystalline Powder
[pka]

3.15±0.10(Predicted)
[color ]

Off-white
[biological source]

rabbit
[BRN ]

5260336
[InChI]

InChI=1S/C9H10O4/c10-5-7-1-3-8(4-2-7)13-6-9(11)12/h1-4,10H,5-6H2,(H,11,12)
[InChIKey]

VUCNQOPCYRJCGQ-UHFFFAOYSA-N
[SMILES]

C(O)(=O)COC1=CC=C(CO)C=C1
[CAS DataBase Reference]

68858-21-9(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

10
[HS Code ]

29189900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Ethyl acetate-->Sulfuric acid-->Petroleum ether-->Chloroform-->Sodium sulfate-->Sodium chloride-->Sodium bicarbonate-->Formaldehyde-->Phenoxyacetic acid
Hazard InformationBack Directory
[Chemical Properties]

Beige powder
[Uses]

4-(Hydroxymethyl)phenoxyacetic acid is a linkage agent used in solid-phase peptide synthesis according to the "FMOC-polyamide" technique.
[reaction suitability]

reagent type: linker
[Synthesis]

To a mixed solution of tetrahydrofuran ( 12 m L) and water ( 8 m L) of the precursor compound ester ( 312 mg , 1.48 mmol) was added lithium hydroxide ( 109 mg, 4.46 mmol) in aqueous solution, the resulting mixture was stirred and reacted at room temperat
Spectrum DetailBack Directory
[Spectrum Detail]

4-(Hydroxymethyl)phenoxyacetic acid(68858-21-9)MS
4-(Hydroxymethyl)phenoxyacetic acid(68858-21-9)1HNMR
4-(Hydroxymethyl)phenoxyacetic acid(68858-21-9)13CNMR
4-(Hydroxymethyl)phenoxyacetic acid(68858-21-9)IR1
4-(Hydroxymethyl)phenoxyacetic acid(68858-21-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-(Hydroxymethyl)phenoxyacetic acid, 98+%(68858-21-9)
[Sigma Aldrich]

68858-21-9(sigmaaldrich)
[TCI AMERICA]

4-(Hydroxymethyl)phenoxyacetic Acid,>98.0%(T)(68858-21-9)
68858-21-9 suppliers list
Company Name: Suzhou Highfine Biotech Co., Ltd  Gold
Telephone: 0512-69209928 18796809688
Website: www.highfine.com
Company Name: Huai'an Enrico Biotech Co., Ltd  Gold
Telephone: 0517-83900106 19962248636
Website: http://enricobio.com/
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.  
Telephone: 18930552037
Website: www.chemicalbook.com/showsupplierproductslist13285/0_en.htm
Company Name: future industrial shanghai co., ltd  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: GL Biochem (Shanghai) Ltd  
Telephone: 21-61263452 13641803416
Website: http://www.glschina.com/
Company Name: Capot Chemical Co., Ltd  
Telephone: +86 (0) 571 85 58 67 18
Website: www.capotchem.com
Company Name: Shanghai Sinch Parmaceuticals Tech. Co. Ltd.  
Telephone: +86-21-54098501
Website: www.sinch.com.cn
Company Name: Adamas Reagent, Ltd.  
Telephone: 400-6009262 15618770481
Website: www.tansoole.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Chemsky (shanghai) International Co.,Ltd  
Telephone: 021-50135380
Website: www.shchemsky.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Maya High Purity Chemicals  
Telephone: +86 (573) 82222445 (0)18006601000 452520369
Website: www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm
Tags:68858-21-9 Related Product Information
122-59-8 3938-96-3 79-14-1 126-11-4 625-45-6 622-47-9 156-38-7 614-75-5 3006-96-0 5026-62-0 1129-35-7 35285-69-9 7153-22-2 68858-21-9