| Identification | More | [Name]
(4-BROMOBUTYL)TRIPHENYLPHOSPHONIUM BROMIDE | [CAS]
7333-63-3 | [Synonyms]
(4-BROMOBUTYL)TRIPHENYLPHOSPHONIUM BROMIDE
(4-Bromobutyl)triphenylphosphonium bromide, 98 % | [Molecular Formula]
C22H23Br2P | [MDL Number]
MFCD00031636 | [Molecular Weight]
478.2 | [MOL File]
7333-63-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
210-213 °C(lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
solid | [Appearance]
White to off-white Solid | [Sensitive ]
Hygroscopic | [BRN ]
3812291 | [InChI]
1S/C22H23BrP.BrH/c23-18-10-11-19-24(20-12-4-1-5-13-20,21-14-6-2-7-15-21)22-16-8-3-9-17-22;/h1-9,12-17H,10-11,18-19H2;1H/q+1;/p-1 | [InChIKey]
BJDNCJGRAMGIRU-UHFFFAOYSA-M | [SMILES]
[Br-].BrCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3 | [CAS DataBase Reference]
7333-63-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29319019 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Reactant involved in:
- Azidification
- C-H activation and β -elimination to product an eight-membered ring system
- 1,3-Dipolar cycloaddition of azides onto alkenes
- Stereoselective SmI2-mediated coupling of unsaturated carbonyl compounds and aldehydes
- Synthesis of D-labeled methylenecyclobutane
- Coupling reactions
| [reaction suitability]
reaction type: C-C Bond Formation |
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