ChemicalBook--->CAS DataBase List--->7477-67-0

7477-67-0

7477-67-0 Structure

7477-67-0 Structure
IdentificationMore
[Name]

BISPYRAZOLONE
[CAS]

7477-67-0
[Synonyms]

3,3-DIMETHYL-1,1-DIPHENYL-(4,4-BI-2-PYRAZOLINE)-5,5-DIONE
3,3'-DIMETHYL-1,1'-DIPHENYL-[4,4'-BI-2-PYRAZOLINE]-5,5'-DIONE
3,3'-DIMETHYL-1,1'-DIPHENYL-4,4'-BI(5-PYRAZOLONE)
3,3'-DIMETHYL-1,1'-DIPHENYL-[4,4'-BIS-2-PYRAZOLINE]-5,5'-DIONE
3,3'-DIMETHYL-1,1'-DIPHENYL-4,4'-DI-2-PYRAZOLINE-5,5'-DIONE
4,4'-BIS(1-PHENYL-3-METHYL-5-PYRAZOLONE)
4,4'-BIS(3-METHYL-1-PHENYL-5-PYRAZOLONE)
BIS(1-PHENYL-3-METHYL-5-PYRAZOLONE)
BIS(3-METHYL-1-PHENYL-5-PYRAZOLONE)
BISPYRAZOLONE
LABOTEST-BB LT00008461
[4,4’-bi-3h-pyrazole]-3,3’-dione,2,2’,4,4’-tetrahydro-5,5’-dimethyl-2,2’-diphe
[4,4’-bi-3H-Pyrazole]-3,3’-dione,2,2’,4,4’-tetrahydro-5,5’-dimethyl-2,2’-diphenyl-
4’-bi-3H-Pyrazole]-3,3’-dione,2,2’,4,4’-tetrahydro-5,5’-dimethyl-2,2’-diphenyl-[4
Bis(1-phenyl-3-methyl-5-pyrazo
BISPYRAZOLONE, FOR THE DETECTION OF CYAN IDE
4,4'-BIS(3-METHYL-1-PHENYL-5-PYRAZOLONE)[FOR DETERMINATION OF CN, VITAMIN B12, ETC] 97+%
BISPYRAZOLONE(4,4''-BIS-(3-METHYL-1-PHENYL-5-PYRAZOLONE))
2,2',4,4'-tetrahydro-5,5'-dimethyl-2,2'-diphenyl-[4,4'-bi-3H-Pyrazole]-3,3'-dione
3,3-DIMETHYL-1,1''-DIPHENYL[4,4''-BI-2-PYRAZOLINE]-5,5''-DIONE 98%
[EINECS(EC#)]

231-282-5
[Molecular Formula]

C20H18N4O2
[MDL Number]

MFCD00020765
[Molecular Weight]

346.38
[MOL File]

7477-67-0.mol
Chemical PropertiesBack Directory
[Appearance]

off-white to cream-yellowish crystalline powder
[Melting point ]

355 °C
[Boiling point ]

481.12°C (rough estimate)
[density ]

1.31
[refractive index ]

1.6620 (estimate)
[storage temp. ]

Refrigerator
[solubility ]

formic acid: 50 mg/mL, clear, yellow
[form ]

crystalline
[pka]

2.15±0.70(Predicted)
[color ]

tan
[BRN ]

572787
[CAS DataBase Reference]

7477-67-0(CAS DataBase Reference)
[EPA Substance Registry System]

[4,4'-Bi-3H-pyrazole]-3,3'-dione, 2,2',4,4'-tetrahydro-5,5'-dimethyl-2,2'-diphenyl- (7477-67-0)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R43:May cause sensitization by skin contact.
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29331990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetic acid-->N-Bromosuccinimide-->Ethyl acetoacetate-->Sodium acetate trihydrate-->Phenylhydrazine-->1H-Pyrazol-5-ol, 3-methyl-4-nitroso-1-phenyl--->4-bromo-3-methyl-1-phenyl-pyrazolin-5-one-->Edaravone-->1,2-Dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one-->Ethanol-->Selenium dioxide-->5-Methyl-2-phenyl-1,2-dihydropyrazol-3-one
[Preparation Products]

4-[(1,5-dihydro-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-ylidene)methyl]-1,2-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one
Hazard InformationBack Directory
[Chemical Properties]

off-white to cream-yellowish crystalline powder
[Uses]

Bispyrazolone is an impurity of Edaravone (E335000).
[Uses]

It is applied as a reagent for the detection and determination of cyanide. It is also used in an experimental procedure, done in order to remove linamarin in starch from cassava roots, by using plant cell wall-degrading enzymes, xylanase and cellulase. It was also used for spectrophotometric determination and quantization of urea in urine samples. It is also used in assay of cyanogenic compounds and determination of ammonia.
Spectrum DetailBack Directory
[Spectrum Detail]

BISPYRAZOLONE(7477-67-0)MS
BISPYRAZOLONE(7477-67-0)IR1
BISPYRAZOLONE(7477-67-0)IR2
BISPYRAZOLONE(7477-67-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bispyrazolone, 98+%(7477-67-0)
[Sigma Aldrich]

7477-67-0(sigmaaldrich)
[TCI AMERICA]

Bis(3-methyl-1-phenyl-5-pyrazolone)  [for Determination of CN, Vitamin B12, etc],>97.0%(T)(7477-67-0)
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