| Identification | More | [Name]
Fluoroglycofen-ethyl | [CAS]
77501-90-7 | [Synonyms]
COMPETE
FLUOROGLYCOFEN-ETHYL
5-(2-chloro-4-(trifluoromethyl)phenoxy)-2-nitro-benzoicaci2-ethoxy-2-ox
5-(2-chloro-4-(trifluoromethyl)phenoxy)-2-nitro-benzoicaciesterwithethy
bas9106h
fluoroglycofen
lglycolate
rh-0265
superblazer
Fluoroglyofene
Fluroglycofen
carboxymethyl-5-(2-chloro-4-(trifluorometnyl)phenoxy)-2-nitrobenzoate
O-(5-(2-chloro-α,α,α-trifluoro-p-tolyloxy)-2-nitrobenzoyl)glycolic acid
5-[2-CHLORO-4-(TRIFLUOROMETHYL)PHENOXY]-2-NITROBENZOIC ACID-ETHOXY-2-OXOETHYL ESTER
fluoroglicofene-ethyl (draft-iso-f)
fluoroglycofen-ethyl (ansi,bsi,iso)
5-[2-CHLORO-4-(TRIFLUOROMETHYL)PHENOXY]-2-NITROBENZOICACID2-ETHOXY-2-OXOETHYLESTER
Ethoxy-2-oxoethyl (5-2-chloro-4-(trifluoromethyl)phenoxy)-2-nitrobenzoate
Ethoxycarbonylmethyl-5-(2-chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate
Fluoroglycofen ethyl ester | [Molecular Formula]
C18H13ClF3NO7 | [MDL Number]
MFCD01632760 | [Molecular Weight]
447.75 | [MOL File]
77501-90-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
65 °C | [Boiling point ]
487.7±45.0 °C(Predicted) | [density ]
1.4996 (estimate) | [storage temp. ]
Hygroscopic, -20°C Freezer, Under inert atmosphere | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [color ]
Pale Yellow to Light Beige | [Water Solubility ]
604ug/L(temperature not stated) | [InChI]
InChI=1S/C18H13ClF3NO7/c1-2-28-16(24)9-29-17(25)12-8-11(4-5-14(12)23(26)27)30-15-6-3-10(7-13(15)19)18(20,21)22/h3-8H,2,9H2,1H3 | [InChIKey]
IPPAUTOBDWNELX-UHFFFAOYSA-N | [SMILES]
C(OCC(OCC)=O)(=O)C1=CC(OC2=CC=C(C(F)(F)F)C=C2Cl)=CC=C1[N+]([O-])=O | [CAS DataBase Reference]
77501-90-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Fluoroglycofen ethyl ester(77501-90-7) | [EPA Substance Registry System]
77501-90-7(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302 | [Precautionary statements ]
P264-P270-P301+P312-P330-P501 | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RTECS ]
DG5643100 | [HS Code ]
29189900 |
| Hazard Information | Back Directory | [Description]
Fluoroglycofen-ethyl is a nitrophenyl ether compound used as a post-emergence herbicide. It has a low aqueous solubility and a low volatility. Under most conditions it tends not to be environmentally persistent. It is moderately toxic to mammals via the oral route. Information on chronic health risks is missing. It is highly toxic to birds and algae but less so to other species. | [Uses]
Fluoroglycofen-ethyl can be used in biological study and agricultural use of pesticide for removing root of Alternanthera philoxeroides. | [Production Methods]
The commercial production of fluoroglycofen-ethyl involves a carefully controlled chemical synthesis process. It begins by mixing acifluorfen, toluene, and a catalyst, then heating the mixture to initiate the reaction. Potassium carbonate is added next, and the temperature is raised to promote further chemical transformation. Ethyl chloroacetate is then introduced, and the mixture is heated to 90–105 DegC to complete the esterification reaction. Once the reaction concludes, the mixture is slowly cooled and extracted using a toluene-water solution to isolate the organic layer. This layer is then distilled to remove any remaining solvents or impurities, yielding high-purity fluoroglycofen-ethyl. | [Mechanism of action]
Induces the accumulation of tetrapyroles which attack plant cells. Inhibition of protoporphyrinogen oxidase (PPO) - cell membrane disruption | [Pesticide Type]
Herbicide |
|
|