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863971-66-8

863971-66-8 Structure

863971-66-8 Structure
IdentificationBack Directory
[Name]

PNN
[CAS]

863971-66-8
[Synonyms]

PNN
2-(DI-T-BUTYLPHOSPHINOMETHYL)-6-(DIETHYLAMINOMETHYL)PYRIDINE
2-((DI-TERT-BUTYLPHOSPHINOMETHYL)-6-DIETHYLAMINOMETHYL)PYRIDINE
2-(Di-t-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine,98%
N-((6-((Di-tert-butylphosphino)Methyl)pyridin-2-yl)Methyl)-N-ethylethanaMine
[Molecular Formula]

C19H35N2P
[MDL Number]

MFCD11656080
[MOL File]

863971-66-8.mol
[Molecular Weight]

322.474
Chemical PropertiesBack Directory
[Boiling point ]

130 °C(Press: 0.02 Torr)
[density ]

0.936 g/mL at 25 °C
[refractive index ]

n20/D1.519
[Fp ]

67℃
[form ]

liquid
[pka]

8.65±0.25(Predicted)
[color ]

yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H261-H315-H319-H335-H413
[Precautionary statements ]

P231+P232-P273-P302+P352-P305+P351+P338
[Hazard Codes ]

F,Xi
[Risk Statements ]

15-36/37/38
[Safety Statements ]

26-36/37-43
[RIDADR ]

UN 3148 4.3 / PGIII
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Ligand/Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
  2. Ligand/ catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
  3. Ligand/Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
  4. Ligand/Catalytic hydrogenation of dimethyl carbonate, methyl carbamates, and methyl formate, a route to methanol based on CO and CO2.
Reactions of 863971-66-8
Hazard InformationBack Directory
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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