ChemicalBook--->CAS DataBase List--->86608-70-0

86608-70-0

86608-70-0 Structure

86608-70-0 Structure
IdentificationMore
[Name]

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
[CAS]

86608-70-0
[Synonyms]

2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSPHONIUM BROMIDE
2-(1,3)-DIOXOLANE-2-YL) ETHYLTRIPHENYLPHOSPHONIUM BROMIDE
2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSP
Phosphonium, 2-(1,3-dioxolan-2-yl)ethyltriphenyl-, bromide
[2-(1,3-dioxalan-2-yl)ethyl]triphenylphosphonium bromide
[EINECS(EC#)]

404-940-6
[Molecular Formula]

C23H24BrO2P
[MDL Number]

MFCD00075119
[Molecular Weight]

443.31
[MOL File]

86608-70-0.mol
Chemical PropertiesBack Directory
[Appearance]

Pale yellow powder
[Melting point ]

144-146 °C(lit.)
[storage temp. ]

Store at room temperature
[solubility ]

soluble in Methanol
[form ]

solid
[color ]

White to Light yellow to Light orange
[BRN ]

5209374
[InChI]

1S/C23H24O2P.BrH/c1-4-10-20(11-5-1)26(21-12-6-2-7-13-21,22-14-8-3-9-15-22)19-16-23-24-17-18-25-23;/h1-15,23H,16-19H2;1H/q+1;/p-1
[InChIKey]

ZCJKBPSRKLHANV-UHFFFAOYSA-M
[SMILES]

[Br-].C1COC(CC[P+](c2ccccc2)(c3ccccc3)c4ccccc4)O1
[CAS DataBase Reference]

86608-70-0(CAS DataBase Reference)
[EPA Substance Registry System]

Phosphonium, [2-(1,3-dioxolan-2-yl)ethyl]triphenyl-, bromide (1:1) (86608-70-0)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R33:Danger of cumulative effects.
R41:Risk of serious damage to eyes.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[WGK Germany ]

2
[F ]

3
[TSCA ]

TSCA listed
[REACH Registrations]

Inactive
[HS Code ]

29322090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
STOT RE 2
Hazard InformationBack Directory
[Chemical Properties]

Pale yellow powder
[Uses]

Reactant for:
  • Wittig olefination
  • Preparationof ligands for histamine receptor binding with H3/H4 subtype selectivity
  • Preparation of dual inhibitors of phosphodiesterase-4 and serotonin reuptake
[Uses]

suzuki reaction
[reaction suitability]

reaction type: C-C Bond Formation
[Synthesis]

In a 100ml four-necked flask equipped with reflux condenser tube (gas absorption device at the top), dropping funnel, stirrer, add 20ml of water, slowly add 24ml of concentrated sulfuric acid, cool down and then add 2-(2-hydroxyethyl)-1,3-dioxane, mix wel
Spectrum DetailBack Directory
[Spectrum Detail]

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)MS
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)1HNMR
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)13CNMR
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)IR1
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)IR2
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide, 97%(86608-70-0)
[Sigma Aldrich]

86608-70-0(sigmaaldrich)
[TCI AMERICA]

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide,>97.0%(T)(86608-70-0)
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