| Identification | More | [Name]
4-Aminobenzonitrile | [CAS]
873-74-5 | [Synonyms]
4-AMINOBENZONITRILE
4-AMINOPHENYLCYANIDE
4-CYANOANILINE
AKOS 91151
AKOS B029065
LABOTEST-BB LT00259453
P-AMINOBENZONITRILE
P-CYANOANILINE
TIMTEC-BB SBB008363
1-Amino-4-cyanobenzene
4-amino-benzonitril
Aniline, p-cyano-
Benzonitrile, p-amino-
p-amino-benzonitril
p-cyano-anilin
4-Aminobenzonitrile
p-Cyanoaniline
p-Aminobenzonitrile 4-Aminobenzonitrile
4-Aminobenzonitrile99%
4-Aminobenzonitrile,98%
Benzonitrile, 4-amino- | [EINECS(EC#)]
212-850-1 | [Molecular Formula]
C7H6N2 | [MDL Number]
MFCD00007821 | [Molecular Weight]
118.14 | [MOL File]
873-74-5.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white or beige to orange-yellow crystalline | [Melting point ]
83-85 °C(lit.)
| [Boiling point ]
167 °C / 1mmHg | [density ]
1.1151 (rough estimate) | [vapor pressure ]
0.002-0.005Pa at 20-25℃ | [refractive index ]
1.5500 (estimate) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder Chunks | [pka]
1.74(at 25℃) | [color ]
Off-white or beige to orange-yellow | [Water Solubility ]
Soluble in ethyl acetate, dichloromethane and chloroform. Insoluble in water. | [Detection Methods]
HPLC | [BRN ]
774507 | [Stability:]
Toxic | [InChI]
1S/C7H6N2/c8-5-6-1-3-7(9)4-2-6/h1-4H,9H2 | [InChIKey]
YBAZINRZQSAIAY-UHFFFAOYSA-N | [SMILES]
Nc1ccc(cc1)C#N | [LogP]
1 at 20℃ and pH7 | [CAS DataBase Reference]
873-74-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzonitrile, 4-amino-(873-74-5) | [Storage Precautions]
Light sensitive | [EPA Substance Registry System]
873-74-5(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS08 | [Signal word ]
Warning | [Hazard statements ]
H302-H341-H412 | [Precautionary statements ]
P202-P264-P270-P273-P301+P312-P308+P313 | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36:Irritating to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 2811 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
BX2320000
| [Hazard Note ]
Harmful | [TSCA ]
T | [REACH Registrations]
Active | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29269095 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Chronic 3
Muta. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
off-white or beige to orange-yellow crystalline | [Uses]
4-Aminobenzonitrile is an amino substituted benzonitrile with hypotensive activity. 4-Aminobenzonitrile is used as radioprotective agent | [Uses]
Usually used as derivatization reagent in capillary zone electrophoretic analysis of aldoses, ketoses and uronic acid,and also used in the synthesis of methacrylic monomers containing pendant azobenzene structures and polythiophenes containing an azobenzene moiety in the side-chain. | [Synthesis]
Mixing the nitrobenzene substituent with ammonia gas and a second gas, and reacting in the presence of a catalyst to obtain the p-aminobenzonitrile, wherein the second gas is air, oxygen or inert gas.
| [Purification Methods]
It crystallises from water, 5% aqueous EtOH or EtOH and is dried over P2O5 or dried in vacuo for 6hours at 40o. [Moore et al. J Am Chem Soc 108 2257 1986, Edidin et al. J Am Chem Soc 109 3945 1987, Beilstein 14 IV 1158.] |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|