ChemicalBook--->CAS DataBase List--->90-01-7

90-01-7

90-01-7 Structure

90-01-7 Structure
IdentificationMore
[Name]

2-Hydroxybenzyl alcohol
[CAS]

90-01-7
[Synonyms]

2-HYDROXYBENZYL ALCOHOL
2-METHYLOLPHENOL
HYDROXYBENZYL-2 ALCOHOL
O-HYDROXYBENZYL ALCOHOL
O-(HYDROXYMETHYL)PHENOL
RARECHEM AL BD 0029
SALICAIN
SALICYL ALCOHOL
SALIGENIN
SALIGENINE
SALIGENOL
,2-Dihydroxytoluene
2-hydroxy-benzenemethano
2-Hydroxybenzenemethanol
2-hydroxy-Benzenemethanol
2-Hydroxymethylphenol
alpha,2-Dihydroxytoluene
alpha-Hydroxy-o-cresol
Benzenemethanol, 2-hydroxy-
Benzyl alcohol, o-hydroxy-
[EINECS(EC#)]

201-960-5
[Molecular Formula]

C7H8O2
[MDL Number]

MFCD00004617
[Molecular Weight]

124.14
[MOL File]

90-01-7.mol
Chemical PropertiesBack Directory
[Appearance]

light brown crystalline powder
[Melting point ]

83-85 °C(lit.)
[Boiling point ]

190.92°C (rough estimate)
[density ]

1,613 g/cm3
[refractive index ]

1.5035 (estimate)
[storage temp. ]

Store below +30°C.
[solubility ]

ethanol: soluble5%, clear to very slightly hazy, colorless to light yellow
[form ]

Crystalline Flakes or Powder
[pka]

pK1:9.92 (25°C)
[color ]

Light beige
[Stability:]

Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents.
[Water Solubility ]

67 g/L (22 ºC)
[Merck ]

14,8325
[BRN ]

1907195
[Major Application]

food and beverages
personal care
[InChI]

1S/C7H8O2/c8-5-6-3-1-2-4-7(6)9/h1-4,8-9H,5H2
[Contact allergens]

Methylol phenols are sensitizers contained in resins based on phenol and formaldehyde of the resol type. Cross-reactivity is possible with other phenol derivative molecules.
[InChIKey]

CQRYARSYNCAZFO-UHFFFAOYSA-N
[SMILES]

OCc1ccccc1O
[LogP]

0.730
[CAS DataBase Reference]

90-01-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Salicyl alcohol(90-01-7)
[EPA Substance Registry System]

90-01-7(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

light brown crystalline powder
[Uses]

2-Hydroxybenzyl Alcohol is a phenolic component of a part of a salix bark extract which maintains a minor anti-depressant effect. Phenolic analog with potential for anti-melanomic effect
[Uses]

anesthetic (local), antiinflammatory
[Definition]

ChEBI: A hydroxybenzyl alcohol that is phenol substituted by a hydroxymethyl group at C-2.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 60, p. 5314, 1995 DOI: 10.1021/jo00121a060
Tetrahedron Letters, 10, p. 1739, 1969
[General Description]

2-Hydroxybenzyl alcohol participates in the selective ring opening reaction of 4H-1,3,2-benzodioxasilines.
[Purification Methods]

Crystallise saligenine from water or EtOH/*C6H6 (m 89o). [Beilstein 6 III 4537, 6 IV 5896.]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H315-H319
[Precautionary statements ]

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

DO6430000
[TSCA ]

Yes
[HS Code ]

29072900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Formaldehyde
[Preparation Products]

Xanthene-->Salithion-->2-Dimethylaminomethylphenol (contains phenol)-->2,2'-Methylenediphenol-->2-Salicylideneaminophenol-->5-(Chloromethyl)-2-hydroxybenzaldehyde-->N,N'-Disalicylal-1,2-phenylenediamine-->Salicylideneaniline-->2,4,4,6-Tetrabromo-2,5-cyclohexadienone-->4H-1,3-Benzodioxin, 2,2-dimethyl--->CHEMBRDG-BB 9070765-->2-(1H-Imidazol-2-ylmethyl)-phenol-->o-Hydroxybenzylchloride
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Hydroxybenzyl alcohol(90-01-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2-Hydroxybenzyl alcohol(90-01-7)MS
2-Hydroxybenzyl alcohol(90-01-7)1HNMR
2-Hydroxybenzyl alcohol(90-01-7)13CNMR
2-Hydroxybenzyl alcohol(90-01-7)IR1
2-Hydroxybenzyl alcohol(90-01-7)IR2
2-Hydroxybenzyl alcohol(90-01-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Hydroxybenzyl alcohol, 97%(90-01-7)
[Alfa Aesar]

2-Hydroxybenzyl alcohol, 99%(90-01-7)
[TCI AMERICA]

2-Hydroxybenzyl Alcohol,>98.0%(GC)(90-01-7)
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