| Identification | More | [Name]
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE | [CAS]
91796-57-5 | [Synonyms]
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE
(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE
(R)-(+)-MENTHYL P-TOLUENESULFINATE
(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER
(+)-(1S)-Menthyl (R)-p-toluenesulfinate
p-Toluenesulfinic acid (1R)-5β-methyl-2β-isopropylcyclohexan-1β-yl ester | [Molecular Formula]
C17H26O2S | [MDL Number]
MFCD00064472 | [Molecular Weight]
294.45 | [MOL File]
91796-57-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
104-106 °C(lit.) | [Boiling point ]
402.3±38.0 °C(Predicted) | [density ]
1.08±0.1 g/cm3(Predicted) | [refractive index ]
200 ° (C=2, Acetone) | [storage temp. ]
−20°C
| [form ]
powder to crystal | [color ]
White to Almost white | [optical activity]
[α]20/D +200°, c = 2 in acetone | [BRN ]
4907352 | [CAS DataBase Reference]
91796-57-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [HS Code ]
2930.90.2900 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate is used as a reactant in the stereoselective synthesis of pyrazole derivatives using tert-butansulfonamide as a chiral auxiliary. | [Uses]
(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:
- As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
- To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
- In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.
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| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
TCI Europe
|
| Tel: |
320-37350700 |
| Website: |
https://www.tcichemicals.com/de/de/index.html |
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