| Identification | Back Directory | [Name]
ISOPROPYLMAGNESIUM BROMIDE | [CAS]
920-39-8 | [Synonyms]
Isopropylbromomagnesium
BroMoisopropylMagnesiuM
2-Propylmagnesium bromide
ISOPROPYLMAGNESIUM BROMIDE
Brom(1-methylethyl)magnesium
bromo(1-methylethyl)magnesium
IsopropylMagnesiuM broMide solution
iso-Propylmagnesiumbromide(15%inTHF)
Isopropylmagnesium bromide, 1.0 M in THF
IsopropylMagnesiuM broMide, 3M in 2-MeTHF
i-Propylmagnesium bromide 1M solution in THF
i-Propylmagnesium bromide 2M solution in DEE
Isopropylmagnesium bromide [1M solution in THF]
Isopropylmagnesium bromide solution 1.0 M in THF
Isopropylmagnesium Bromide 2.0 M In Diethyl Ether
ISOPROPYLMAGNESIUM BROMIDE: 15% IN TETRAHYDROFURAN
Isopropylmagnesium Bromide 1.0 M In Tetrahydrofuran
i-Propylmagnesium bromide 2.75M solution in 2-MeTHF
ISOPROPYLMAGNESIUM BROMIDE, 0.8 M in TETRAHYDROFURAN
Isopropyl magnesium bromide 3M 2- methyltetrahydrofuran
IsopropylMagnesiuM broMide, 1.0 M solution in THF, J&KSeal
IsopropylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal
IsopropylMagnesiuM broMide, 3M solution in 2-MeTHF, AcroSeal
Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L)
IsopropylMagnesiuM broMide, 2.0 M solution in 2-Me THF, J&KSeal
IsopropylMagnesiuM broMide, 3.0 M solution in 2-Me THF, J&KSeal
Isopropylmagnesium bromide,3M solution in 2-Methyltetrahydrofuran
Isopropylmagnesium bromide solution 2.9 M in 2-methyltetrahydrofuran
IsopropylMagnesiuM broMide, 3.0 M in 2-Methyltetrahydrofuran, SpcSeal
i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran
Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal
Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal§3 | [EINECS(EC#)]
213-056-8 | [Molecular Formula]
C3H7BrMg | [MDL Number]
MFCD00672110 | [MOL File]
920-39-8.mol | [Molecular Weight]
147.3 |
| Chemical Properties | Back Directory | [Appearance]
Clear dark brown or dark gray solution | [Melting point ]
114-116℃ | [Boiling point ]
148-154℃ | [density ]
0.982 g/mL at 25 °C | [Fp ]
-17°C | [storage temp. ]
2-8°C | [solubility ]
Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons. | [form ]
Solution | [color ]
Clear dark brown or dark gray | [Sensitive ]
Air & Moisture Sensitive | [InChI]
InChI=1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1 | [InChIKey]
UCJIVFREPMUZDC-UHFFFAOYSA-M | [SMILES]
C(C)(C)[Mg]Br | [EPA Substance Registry System]
Magnesium, bromo(1-methylethyl)- (920-39-8) |
| Hazard Information | Back Directory | [Chemical Properties]
Clear dark brown or dark gray solution | [Uses]
Isopropylmagnesium bromide is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.9 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information. | [reaction suitability]
reaction type: Grignard Reaction | [Synthesis]
Nitrogen was replaced 3 times in a 500L reactor, 25.25kg of magnesium balls (0.8cm) were added, 100L of 2-methyltetrahydro was added and the initiator (2-bromopropane Grignard reagent) was 2kg.
furan and initiator (2-bromopropane Grignard reagent) 2kg, h |
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