| Identification | Back Directory | [Name]
PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY& | [CAS]
92361-49-4 | [Synonyms]
Cp*RuCl(PPh3)2
phosphine)ruthenium(II) chL
Chloro(pentamethylcyclopentadienyl)
PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY&
Chloro(η5-pentamethylcyclopentadiene)[bis(triphenylphosphine)]ruthenium
Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chlorid
Chloro(pentaMethylcyclopentadienyl)bis(triphenylphosphine)rutheniuM(II),99%
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II),98%
chlororuthenium(1+),1,2,3,4,5-pentamethylcyclopenta-1,3-diene,triphenylphosphane
Ruthenium,chloro[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]bis(triphenylphosphine)- | [Molecular Formula]
C46H47ClP2Ru | [MDL Number]
MFCD09038426 | [MOL File]
92361-49-4.mol | [Molecular Weight]
798.35 |
| Chemical Properties | Back Directory | [Melting point ]
128 °C (D) | [storage temp. ]
2-8°C | [solubility ]
Soluble in dichloromethane, chloroform, toluene, tetrahydrofuran. | [form ]
Powder | [color ]
orange | [Sensitive ]
Air Sensitive | [Stability:]
store cold | [InChI]
InChI=1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;-1;;/p+1 | [InChIKey]
BIQPPPXMBGVBDQ-UHFFFAOYSA-O | [SMILES]
P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Ru+2]1234(C5(C)=C1(C)C2(C)=C3(C)[C-]45C)([Cl-])P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1 |
| Hazard Information | Back Directory | [Uses]
Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions". | [reaction suitability]
core: ruthenium
reagent type: catalyst
reaction type: click chemistry |
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