| Identification | More | [Name]
Pentamethylcyclopentadienyltitanium trichloride | [CAS]
12129-06-5 | [Synonyms]
PENTAMETHYLCYCLOPENTADIENE TITANIUM TRICHLORIDE
(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV) TRICHLORIDE
PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRICHLORIDE
TRICHLORO(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV)
eta5-Pentamethylcyclopentadienyl
pentamethylcyclopentadienyltitaniumtrochloride
Titanium, eta5-pentamethylcyclopentadienyl trichloride)-
PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRICHLORIDE 98%
Pentamethylcyclopentadienyltitaniumtrichloride,98% | [Molecular Formula]
C10H15Cl3Ti | [MDL Number]
MFCD00070434 | [Molecular Weight]
289.45 | [MOL File]
12129-06-5.mol |
| Chemical Properties | Back Directory | [Appearance]
red to bordeaux crystals | [Melting point ]
200 °C (dec.) (lit.) | [Boiling point ]
190-220 °C(Press: 4-7 Torr) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
crystal | [color ]
red | [Water Solubility ]
reacts | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C10H15.3ClH.Ti/c1-6-7(2)9(4)10(5)8(6)3;;;;/h1-5H3;3*1H;/q;;;;+3/p-3 | [InChIKey]
QCEOZLISXJGWSW-UHFFFAOYSA-K | [SMILES]
[C]1([C](C)[C](C)[C](C)[C]1C)C.[Ti](Cl)(Cl)Cl |^1:0,1,3,5,7| | [CAS DataBase Reference]
12129-06-5(CAS DataBase Reference) | [NIST Chemistry Reference]
«eta»5-Pentamethylcyclopentadienyl titanium trichloride(12129-06-5) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29319090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Description]
Trichloro(pentamethylcyclopentadienyl)titanium(IV) is a versatile catalyst for transesterification reactions and styrene polymerization. | [Chemical Properties]
red to bordeaux crystals | [Uses]
It is used as a catalyst in Transesterification reactions and styrene polymerization. It is also used as Piano-stool catalyst. | [General Description]
Pentamethylcyclopentadienyltitanium trichloride has been shown to have mononuclear structure and high molecular weight, which can be confirmed by its crystal x-ray diffraction pattern. It belongs to the class of syndiotactic compounds and has an MM value of 1.3 g/mol. It also has a high degree of crystallinity, which can be seen from its diffraction pattern on a hexamethylenetetramine plate. | [reaction suitability]
core: titanium
reagent type: catalyst |
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